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Photodissociation dynamics of carbon dioxide cation via the vibrationally mediated state: A time-sliced velocity-mapped ion imaging study
Rui Mao
Author NameAffiliationE-mail
Rui Mao Changzhou Institute of Technology maorui@ustc.edu.cn 
Abstract:
We report on the photodissociation dynamics of cation via its state using the scheme of [1 1] photon excitation that is intermediated by the mode-selected vibronic states. Photodissociation fragment exciation spectrum and images of fragment have been measured to obtain reaction dynamics parameters such as the available energy and the average translational energy. Combing with the potential energy functions of cation, the dissociation mechanism is discussed. The conformational variation of cation from linear to bent on the photodissociation dynamics of cation is verified.
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FundProject:
Photodissociation dynamics of carbon dioxide cation via the vibrationally mediated state: A time-sliced velocity-mapped ion imaging study
茆锐
摘要:
We report on the photodissociation dynamics of cation via its state using the scheme of [1 1] photon excitation that is intermediated by the mode-selected vibronic states. Photodissociation fragment exciation spectrum and images of fragment have been measured to obtain reaction dynamics parameters such as the available energy and the average translational energy. Combing with the potential energy functions of cation, the dissociation mechanism is discussed. The conformational variation of cation from linear to bent on the photodissociation dynamics of cation is verified.
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