Volume 33 Issue 1
Apr.  2020
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Hao Wu, Jian Chen, An-wen Liu, Shui-ming Hu, Jing-song Zhang. Cavity Ring-Down Spectroscopy Measurements of Ambient NO$_\bf{3}$ and N$_\bf{2}$O$_\bf{5}$[J]. Chinese Journal of Chemical Physics , 2020, 33(1): 1-7. doi: 10.1063/1674-0068/cjcp1910173
Citation: Hao Wu, Jian Chen, An-wen Liu, Shui-ming Hu, Jing-song Zhang. Cavity Ring-Down Spectroscopy Measurements of Ambient NO$_\bf{3}$ and N$_\bf{2}$O$_\bf{5}$[J]. Chinese Journal of Chemical Physics , 2020, 33(1): 1-7. doi: 10.1063/1674-0068/cjcp1910173

Cavity Ring-Down Spectroscopy Measurements of Ambient NO$_\bf{3}$ and N$_\bf{2}$O$_\bf{5}$

doi: 10.1063/1674-0068/cjcp1910173
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  • Corresponding author: Shui-ming Hu, E-mail: smhu@ustc.edu.cn
  • Received Date: 2019-10-06
  • Accepted Date: 2019-12-02
  • Publish Date: 2020-02-27
  • NO$_3$ and N$_2$O$_5$ are important participants in nocturnal atmospheric chemical processes, and their concentrations are of great significance in the study of the mechanism of nocturnal atmospheric chemical reactions. A two-channel diode laser based cavity ring-down spectroscopy (CRDS) instrument was developed to monitor the concentrations of NO$_3$ and N$_2$O$_5$ in the atmosphere. The effective absorption length ratio and the total loss coefficient of the instrument were calibrated using laboratory standard samples. The effective absorption cross section of NO$_3$ at 662 nm was derived. A detection sensitivity of 1.1 pptv NO$_3$ in air was obtained at a time resolution of 1 s. N$_2$O$_5$ was converted to NO$_3$ and detected online in the second CRDS channel. The instrument was used to monitor the concentrations of NO$_3$ and N$_2$O$_5$ in the atmosphere of winter in Hefei in real time. By comparing the concentration changes of pollutants such as nitrogen oxides, ozone, PM$_{2.5}$ in a rapid air cleaning process, the factors affecting the concentrations of NO$_3$ and N$_2$O$_5$ in the atmosphere were discussed.


  • Part of The special topic on "The 3rd Asian Workshop on Molecular Spectroscopy"
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