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束源转动的交叉分子束装置及其在分子簇动力学研究中的应用

Rotatable Crossed Molecular Beam Machine and Its Application in Cluster Dynamics Studies

  • 摘要: 本文报道的束源转动的交叉分子束装置有两个互相垂直交叉并且可同步绕一固定轴转动的脉冲束源,激光束可沿上述轴线方向与两束交叉.控测器是一四极质谱,它与散射中心的距离可以调节,探测方向固定不变与两个分子束在同一平面内并指向散射中心.质谱产生的离子信号用高灵敏度的Daly系统接收.该设备将用于研究分子簇的形成和裂解.分子或分子簇的光解和两分子束的交叉散射过程.用这台设备我们测量了在CO2和NH3超声束中形成的各种Clustcr的质谱图以及(CO2)nClustcr束与Ar束的散射的角分布.

     

    Abstract: A rotatable cross molecular beam machine discribed here consists of two pulsed beam units which are perpedicular to each other and are able to rotate synchronously about a certain axis along which a laser beam can cross with the molecular beams. The apparatus is equipped with a translationally movable ultrahigh vacuum mass spectrameter for time of flight (TOF)measurement. The detecting direction orients coplanarly with both molecular beams. The ions coming out of the mass filter are collected by a sensitive Dalytype detector. The apparatus is available for studies of formation of clusters, photolysis of molecules or clusters and collision of two particle beams. In this equipment the mass spectra of the clusters (CO2)n and (NH3)nformed in CO2 and NH3 supersonic expansion beams were measured respectively. The Angular Distribution (Lab) of CO2+ arising from the collision of (CO2)n with Ar was also reported.

     

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