卟啉和卟啉铜分子的成膜特性和UV-Vis光谱表征

Forming-film Properties and UV-Vis Spectroscopic Characterization of Porphyrin and Copper Porphyrin

摘要: 合成了5，10，15，20-四（对-异戊酯苯基）卟啉及其铜配合物，研究了它们在气液界面的成膜性质，制备了上述化合物的LB膜，利用UV-Vis光谱对化合物在LB膜结构中的取向进行了表征.研究结果表明.两种化合物在界面上的成膜性质和分子环面在LB膜结构中的取向均受到铜离子配位的影响.

Abstract: 5,10,15,20-tetra （p-isoamoxycarbonphcnyl） porphyrin （abbriviated as H₂IAPP） and its copper complex （CuIAPP） were synthesized and their structure were verified by elemental anylysis and spectral date. The forming-film properties at air-water interface and molecules orientation in LB films of CuIAPP and H₂IAPP were studied. The results were compared.