N2第一正带的塞曼调制磁旋转光谱分析
Analysis of the Zeeman-modulation Magnetic-Rotation Spectroscopy of the First Positive Band of N2
-
摘要: 在17079~17407cm-1范围内,利用了塞曼调制磁旋转光谱技术测量了N2分子第一正带B3∏g~A3∑u+的(10,6)、(11,7)、(12,8)带的近900条谱线,其中包括了用以往各种光谱技术很难观测到的P13、Q13、R13和P31、Q31、R31支线,给出了量子态的标识,并且拟合出相应的转动分子常数。Abstract: The (10,6),(11,7),(12,8)bands of the first positive band B3∏g~A3∑u+ of N2 are analyzed via Zeeman-modulation Magnetic-Rotation Spestroscopy in the range of 17079~17407cm-1 .Near 900 spectral lines are labeled,including P13 、Q13 、R13 and P31 、Q31 、R31 branches which have scarcely been observed before,and the improved molecular rotation constants for v=6,7,8 levels of A state and for the v=10,11,12 levels of B state have been obtained by the means of the nonlinear least squares fitting.