• 中文核心期刊要目总览
  • 中国科技核心期刊
  • 中国科学引文数据库(CSCD)
  • 中国科技论文与引文数据库(CSTPCD)
  • 中国学术期刊文摘数据库(CSAD)
  • 中国学术期刊(网络版)(CNKI)
  • 中文科技期刊数据库
  • 万方数据知识服务平台
  • 中国超星期刊域出版平台
  • 国家科技学术期刊开放平台
  • 荷兰文摘与引文数据库(SCOPUS)
  • 日本科学技术振兴机构数据库(JST)

交叉分子束研究氟原子与1,2-丁二烯反应动力学

Crossed Beams Study on the Dynamics of F Atom Reaction with 1,2-Butadiene

  • 摘要: 利用通用型交叉分子束研究了氟原子与1,2-丁二烯的反应,观测到了C4H5F+H反应通道. 测量产物C4H5FF在实验坐标下的角度分辨的飞行时间谱,获得了这个通道质心坐标下的产物角分布和动能分布. 实验结果表明,相对于氟原子束方向,产物C4H5FF主要是后向散射,同时也有大量的前向散射. 这表明反应通道主要通过长寿命的络合物形成机理进行的,同时也伴有直接的双分子亲核取代反应(SN2)机理.

     

    Abstract: We have investigated the dynamics of the F+C4H6 reaction using the universal crossed molecular beam method. The C4H5F+H reaction channel was observed in this experiment. Angular resolved time-of-flight spectra have been measured for the C4H5F product. Product angular distributions as well as kinetic energy distributions were determined for this product channel. Experimental results show that the C4H5F product is largely backward scattered with considerable forward scattering signal, relative to the F atom beam direction. This suggests that the reaction channel mainly proceeds via a long-lived complex formation mechanism, with possible contribution from a direct SN2 type mechanism.

     

/

返回文章
返回