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铒掺杂硼酸盐玻璃中的激发态阱

Excited State Trap in Erbium Doped Borate Glass

  • 摘要: 铒掺杂硼酸盐玻璃广泛应用于发光材料中,研究其发光动力学性质对于优化和提高其发光效率具有重要意义. 本文采用传统的熔融淬火法合成了摩尔比为2%的掺铒硼酸盐玻璃,并在低于硼酸盐玻璃转变温度(260 ^\circC)下退火,退火处理后的掺铒硼酸盐玻璃光学性质得到了一定程度的提高. 硼酸盐玻璃未掺杂和掺杂Er^3+的热性能采用差示扫描量热法以10 ^\circC/min的速度进行测量. 同时还测量了掺铒硼酸盐玻璃发光机理的吸收光谱、激发光谱、稳态发射光谱、瞬态发射光谱和衰减动力学曲线. 实验结果表明Er^3+在不同激发波长下556 nm处发射时具有不同的寿命,在掺铒硼酸盐玻璃中可能存在激发态阱,利用实验数据得到了激发态阱的深度为0.14 eV.

     

    Abstract: Erbium doped borate glass is widely used in luminescent materials, the luminescence dynamics of erbium doped borate glass is of great significance for optimizing and improving the luminous efficiency. The 2% molar ratio erbium doped borate glass was synthesized by the traditional melt quenching method, and annealed at 260 ^\circC below the borate glass transition temperature. The thermal performance parameters of borate glass undoped and doped with Er^3+ were measured by differential scanning calorimetry with 10 ^\circC/min. The transient emission spectrum and decay kinetics curves were measured for the luminescence mechanism of erbium doped borate. Er^3+ ions have different lifetime when emitted at 556 nm with different excitation wavelengths, the excited state trap may exist in erbium doped borate glass.

     

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