• 中文核心期刊要目总览
  • 中国科技核心期刊
  • 中国科学引文数据库(CSCD)
  • 中国科技论文与引文数据库(CSTPCD)
  • 中国学术期刊文摘数据库(CSAD)
  • 中国学术期刊(网络版)(CNKI)
  • 中文科技期刊数据库
  • 万方数据知识服务平台
  • 中国超星期刊域出版平台
  • 国家科技学术期刊开放平台
  • 荷兰文摘与引文数据库(SCOPUS)
  • 日本科学技术振兴机构数据库(JST)

羧甲基纤维素增强的离子水凝胶纤维实现防水性和可拉伸性

Water-Resistant and Stretchable Conductive Ionic Hydrogel Fibers Reinforced by Carboxymethyl Cellulose

  • 摘要: 导电离子凝胶被广泛用于开发可拉伸电子器件,包括传感器、电极、驱动器等. 大多数现有的导电离子凝胶材料被制成块状或者片状来使用,由于材料较低的力学性能,现有的导电离子凝胶材料很难被制备成纤维状(水凝胶纤维). 本文用凝胶纺丝的方法制备了一类兼具高强度、良好可拉伸性和良好导电性的CIH纤维. 这类强韧的导电离子凝胶纤维是从聚丙烯酸钠和羧甲基纤维素钠形成的复合凝胶中拉伸纺丝所得. 在这种导电离子凝胶纤维中,聚丙烯酸钠(PAAS)作为软组分,提供良好的导电性和可拉伸性;羧甲基纤维素钠(CMC)作为硬组分,赋予导电离子凝胶纤维较高的强度和韧性. 在纤维表面涂敷一层疏水的聚丙烯酸甲酯(PMA)或者聚丙烯酸丁酯(PBA)作为防水保护层和绝缘层. 所得的PAAS/CMC-PMA和PAAS/CMC-PBA导电离子凝胶纤维兼具高强度(28兆帕)、高韧性(43 MJ/m3)和高导电性(0.35 S/m),可以在基于织物的可拉伸电子器件中得到应用.

     

    Abstract: Conductive ionic hydrogels (CIH) have been widely studied for the development of stretchable electronic devices, such as sensors, electrodes, and actuators. Most of these CIH are made into 3D or 2D shape, while 1D CIH (hydrogel fibers) is often difficult to make because of the low mechanical robustness of common CIH. Herein, we use gel spinning method to prepare a robust CIH fiber with high strength, large stretchability, and good conductivity. The robust CIH fiber is drawn from the composite gel of sodium polyacrylate (PAAS) and sodium carboxymethyl cellulose (CMC). In the composite CIH fiber, the soft PAAS presents good conductivity and stretchability, while the rigid CMC significantly enhances the strength and toughness of the PAAS/CMC fiber. To protect the conductive PAAS/CMC fiber from damage by water, a thin layer of hydrophobic polymethyl acrylate (PMA) or polybutyl acrylate (PBA) is coated on the PAAS/CMC fiber as a water-resistant and insulating cover. The obtained PAAS/CMC-PMA and PAAS/CMC-PBA CIH fibers present high tensile strength (up to 28 MPa), high tensile toughness (up to 43 MJ/m3), and good electrical conductivity (up to 0.35 S/m), which are useful for textile-based stretchable electronic devices.

     

/

返回文章
返回