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    Tang Yuhong, Liu Quanliang, Hu Zhaolin, Hou Yinlan. Oscillations and Chaos in the BZ Reactions of o-NH2C6H4COOH System──Ⅱ. Model and Numerical Results[J]. Chinese Journal of Chemical Physics , 1994, 7(5): 480-486.
    Citation: Tang Yuhong, Liu Quanliang, Hu Zhaolin, Hou Yinlan. Oscillations and Chaos in the BZ Reactions of o-NH2C6H4COOH System──Ⅱ. Model and Numerical Results[J]. Chinese Journal of Chemical Physics , 1994, 7(5): 480-486.

    Oscillations and Chaos in the BZ Reactions of o-NH2C6H4COOH System──Ⅱ. Model and Numerical Results

    • On the basis of analysis of the oscillations and chaos in the o-NH2C6H4COOH BZ reaction system reproted in paper I, this paper proposes a reasonable Otegonator type model about BZ oscillation reactions, and simulates the oscillating and chaotic behaviors corresponding those observed in cxperiments. The numerical results are compared with the experimental results in the view of the potential-time curve of bromide, phase space, Poincare map, first return map and fractal dimension, and indicate that the model can simulated the periodic oscillations and chaotic oscillations qualitively. The studies on the medium products lead to a found that the concentrations of HBrO2 and HOBr change monotonously during the small amplitude oscillations of the concentration of Br- before a large-amplitude excursion, which suggests that HBrO2 and HOBr maybe not take a part in small amplitude oscillations. Moreover, the influences of some unreliable parameters on oscillaton behaviors arc discussed.
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