Solid State Redox Reaction ofFe(bpy)3 (ClO4)3·3H2O with Sodium Sulfite at Room Temperature

Zhang Weihua; Xu Yangzi; Xin Xinquan

Zhang Weihua, Xu Yangzi, Xin Xinquan. Solid State Redox Reaction of[Fe(bpy)3] (ClO4)3·3H2O with Sodium Sulfite at Room Temperature[J]. Chinese Journal of Chemical Physics , 1995, 8(6): 564-568.

Citation:

Zhang Weihua, Xu Yangzi, Xin Xinquan. Solid State Redox Reaction of[Fe(bpy)3] (ClO4)3·3H2O with Sodium Sulfite at Room Temperature[J]. Chinese Journal of Chemical Physics , 1995, 8(6): 564-568.

Citation:

Zhang Weihua, Xu Yangzi, Xin Xinquan. Solid State Redox Reaction of[Fe(bpy)3] (ClO4)3·3H2O with Sodium Sulfite at Room Temperature[J]. Chinese Journal of Chemical Physics , 1995, 8(6): 564-568.

Solid State Redox Reaction ofFe(bpy)₃ (ClO₄)₃·3H₂O with Sodium Sulfite at Room Temperature

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Abstract

Intersection face moving seethed is designed to study the solid state redox reaction ofFe （bpy）₃（ClO₄）₃·3H₂O with sodium sulfite at room temperature. Mossbauer spectrometry, XRD, FTIR, Magnetic susceptibility and Elemental analysis Were used to characterize the solid state redox reaction product. In this system, the interface chemical reaction is the rate determined step of the apparent reaction,and the activation energy is calaulated as 78. 2kJ. mol^-1.

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Solid State Redox Reaction ofFe(bpy)3 (ClO4)3·3H2O with Sodium Sulfite at Room Temperature

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Solid State Redox Reaction ofFe(bpy)₃ (ClO₄)₃·3H₂O with Sodium Sulfite at Room Temperature