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Fractal Study of Mesoporous Structure in Water Molecular Condensed System
Li Wang ,Ya-jiang Yang*
Author NameAffiliation
Li Wang Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074, China 
Ya-jiang Yang* Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074, China 
Abstract:
Bis-(4-stearoylaminophenyl) ether (BSADE) can aggregate and self-assemble in water. Transmission electron microscopy (TEM) indicated that the morphology of BSADE aggregates in water was entanglement and thin fiber-like, and that a three dimensional network structure was formed. Water molecules were entrapped in this three dimensional network structure and formed a new type of condensed system (so-called water molecular gel). Water molecular gel is a typical mesoporous material which can be characterized by the fractal dimension D. Using gas adsorption method along with measurement of porosity and specific surface area, the fractal dimension D of the complicated pores was 2.1-2.2 for this water molecular gel. Using viscosity method and the Cayley fractal tree, the fractal dimension D of the fiber-like three dimensional network was determined to be 1.98. The formation process of water molecular gel can be described as nucleation followed by a repeated growing and branching cycle.
Key words:  Fractal, Mesoporous structure, Water molecular condensed system
FundProject:
水分子凝聚体系的介孔结构分形学
王理,杨亚江*
摘要:
透射电镜研究表明,4,40-双硬脂酰胺基二苯醚在水中聚集、自组装成缠绕细纤维状聚集体,进而使整个体系形成三维网络结构.水分子被包囊在这个网络结构中,形成一种新型的凝聚体系(水分子凝胶).水分子凝胶是一种典型的纳米介孔物质,其复杂的微孔结构可以用分形维数D来表征,通过气体吸附方法(孔度法和比表面积法)计算,求得水分子凝胶体系的微孔结构的分形维数为2.1?2.2.对于纤维状三维网络结构的分形表征,通过粘度法和Cayley分形树模型得出分形维数为1.98.由此推测其分形网络形成的过程是一个初始成核-生长-枝化的循环过程.
关键词:  分形,介孔结构,水分子凝聚体系
DOI:10.1360/cjcp2007.20(1).17.5
分类号: