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Synthesis, Characterization and Photovoltaic Effect of Porphyrin-Fullerene Compounds MP-C60
Yang Sengen*, Fan Suhua, Liu Jianyong, Wu Zhenyi, Tian Ling, Lin Yongsheng, Zhan Mengxiong
Department of Chemistry, Xiamen University, Xiamen 361005
Abstract:
The convalently linked porphyrin-fullerene ligand was synthesized by 1,3 dipolar cycloaddition reaction. The ligand and complexes were characterized by means of FT-IR, Uv-Vis, 1HNMR, ESI-MS and elemental analysis. The photoelectricity transform performance of the compounds was studied.The result indicated that the photovoltaic effect of (n+n) heterojunction electrode formed by MP-C60/GaAs was super, especially in the I2/I3- and O2/H2O redox couples, and photovoltaic potential was preferable. The photovoltaic performance of a MP-C60/GaAs electrode at 1-2 μm thinck MP-C60 film of appeared peak value.
Key words:  Porphyrin, Fullerene, Photovoltaic effect
FundProject:
MP-C60(M=Cu,Co)化合物的合成、表征及光电性能研究
杨森根*, 凡素华, 刘见永, 吴振奕, 田玲, 林永生, 詹梦熊
厦门大学化学系, 厦门 361005
摘要:
关键词:  卟啉  富勒烯  光电性能
DOI:10.1088/1674-0068/18/5/654-656
分类号: