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Relabeling of the Rydberg and Doubly Excited States of Li2
Song Min, Liu Yaoming, Li Li*
Department of Physics and Key Laboratory of Atomic and Molecular Nanosciences,Tsinghua University,Beijing 100084
Abstract:
68 electronic states of 7Li2 observed and/or calculated have been relabeled according to the dominant hydrogenic nlλ characters of the Rydberg orbitals and classified as core-penetrating vs core-nonpenetrating states. The perturbations between doubly excited valence states and Rydberg states are discussed. The significance of this labeling is also discussed.
Key words:  Li2, 7Li2, Rydberg state, Core-penetrating, Core-nonpenetrating states, Doubly excited state
FundProject:
锂分子里德堡态和双激发态的重新分类
宋敏, 刘耀明, 李丽*
清华大学物理系原子分子纳米科学教育部重点实验室,北京,100084
摘要:
根据里德堡轨道的类氢nλ特性,对 7Li2实验已观测到的和理论计算给出的68个电子态进行了分类,把这些态划分为核实贯穿里德堡态和核实非贯穿里德堡态.讨论了双电子激发态和里德堡态的微扰,也讨论了这种分类的意义.
关键词:  
DOI:10.1088/1674-0068/15/3/207-212
分类号: