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Relabeling of the Rydberg and Doubly Excited States of Li2
Song Min,Liu Yaoming,Li Li*
Author NameAffiliationE-mail
Song Min Department of Physics and Key Laboratory of Atomic and Molecular NanosciencesTsinghua UniversityBeijing 100084  
Liu Yaoming Department of Physics and Key Laboratory of Atomic and Molecular NanosciencesTsinghua UniversityBeijing 100084  
Li Li* Department of Physics and Key Laboratory of Atomic and Molecular NanosciencesTsinghua UniversityBeijing 100084 lili@lsad.tsinghua.edu.cn 
Abstract:
68 electronic states of 7Li2 observed and/or calculated have been relabeled according to the dominant hydrogenic nlλ characters of the Rydberg orbitals and classified as core-penetrating vs core-nonpenetrating states. The perturbations between doubly excited valence states and Rydberg states are discussed. The significance of this labeling is also discussed.
Key words:  Li2, 7Li2, Rydberg state, Core-penetrating, Core-nonpenetrating states, Doubly excited state
FundProject:
锂分子里德堡态和双激发态的重新分类
宋敏,刘耀明,李丽*
摘要:
根据里德堡轨道的类氢nλ特性,对 7Li2实验已观测到的和理论计算给出的68个电子态进行了分类,把这些态划分为核实贯穿里德堡态和核实非贯穿里德堡态.讨论了双电子激发态和里德堡态的微扰,也讨论了这种分类的意义.
关键词:  
DOI:10.1088/1674-0068/15/3/207-212
分类号: