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A Study on the Reaction of HCO with NO
Dong Feng,Lu Zhou,Kong Fanao
Author NameAffiliation
Dong Feng State Key Laboratory of Molecular Reaction Dynamics, Center of Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080 
Lu Zhou State Key Laboratory of Molecular Reaction Dynamics, Center of Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080 
Kong Fanao State Key Laboratory of Molecular Reaction Dynamics, Center of Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080 
Abstract:
The reaction of formyl radical HCO with NO was investigated by Time-Resovled Fourier Transform Infrared(TR-FTIR) spectroscopy. Vibrationally excited products CO and HNO were observed. The HNO(ν1) spectrum consists of (200-100) and (100-000) bands. Spectral simulation of provides vibrational population of the CO product at 41μs. The vibrational excited CO (v≤4) was found. The results indicate that the major product channel of HCO+NO is HNO+CO.
Key words:  HCO, NO, HNO, FTIR
FundProject:
1HCO自由基与NO反应的研究
董锋,陆洲,孔繁敖
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