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Photoionization Dynamics in the Intense Femtosecond Laser Field by Analyzing Massand Photoelectron Spectrum
Yang Song, Jiang Bo, Sha Guohe, Xu Dali, Lou Nanquan, Xie Jinchun
State Key Laboratory of Molecular Reaction Dynamics,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023
Abstract:
The photoionization dynamics of ammonia and benzene was studied by home-built femtosecond laser and TOF mass/photoelectron spectrometer.Beam intensities of 1012W/cm2 were used with laser pulse width of 100fs and wavelength of 407.5nm.In the PE spectra of NH3,three(2+2)REMPI and (2+2)+1 ATI,(2+2)+2 ATI were shown,within each peak a progression of stretchin gvibrations v1 were found.The vibrational distribution of ATI peaks are inverted compared to normal(2+2)REMPI.High laser power has also caused band broadening and shifting effect,which are given rise to by the pondromotive potential of intense laser.Differ-ent from that of nanosecond,benzene phtoionization using femtosecond laser has predominent molecular ion peak with very small percentage of fragments.
Key words:  Intense field,Femtosecond laser,Photoelectron spectrum
FundProject:国家自然科学基金委重点基金项目(No.298330809)
用质谱和光电子能谱研究飞秒强场中的电离动力学
杨淞, 姜波, 沙国河, 徐大力, 楼南泉, 解金春
中国科学院大连化学物理研究所分子反应动力学国家重点实验室大连 116023
摘要:
报导了用自制飞秒激光器通过飞秒多光子电离质谱和光电子能谱对飞秒强激光场与分子(氨、苯)相互作用的研究。飞秒激光脉宽约100fs,二倍频中心波长407.5nm,聚焦后脉冲功率密度达到10 12W/cm2。氨的光电子能谱显示了(2+2)REMPI和(2+2)+1ATI、(2+2)+2ATI三组电子峰,每组峰又包括伸缩振动v1的带系,ATI峰的振动布居出现反转。随着光强增加,谱峰加宽而且振动能级出现平移。这些强场效应可用Ponderomotive Potential解释。苯的飞秒质谱图与纳秒情况不同,分子离子为
关键词:  强激光场  飞秒激光  光电子能谱
DOI:10.1088/1674-0068/13/4/413-418
分类号: