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Sol-gel Transition of Methylcellulose Solution in the Coexistence of Hexadecyltrimethylammonium Bromide and Sodium Chloride
Shan Zhou,Hai-yang Yang*,Yong-jun Xie,Hua-zhen Li,Guang-ming Liu
Author NameAffiliationE-mail
Shan Zhou CAS Key Lab of Soft Matter Chemistry, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China  
Hai-yang Yang* CAS Key Lab of Soft Matter Chemistry, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China yhy@ustc.edu.cn 
Yong-jun Xie CAS Key Lab of Soft Matter Chemistry, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China  
Hua-zhen Li CAS Key Lab of Soft Matter Chemistry, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China  
Guang-ming Liu CAS Key Lab of Soft Matter Chemistry, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China  
Abstract:
The sol-gel transition of methylcellulose (MC) solution in the presence of NaCl and hexade-cyltrimethylammonium bromide (HTAB), together with MC/NaCl solution in the presence of HTAB and MC/HATB solution in the presence of NaCl, was investigated by the rheolog-ical measurements. It has been found that the sol-gel transition temperature of MC solution decreases linearly with the concentration of NaCl in solution but increases linearly with the concentration of HTAB in solution, respectively. However, the sol-gel transition temperature of MC/NaCl solution in the presence of HTAB keeps the same value, independent of the concentration of HTAB in solution. On the other hand, the sol-gel transition temperature of MC/HTAB solution decreases linearly with the concentration of NaCl in solution. The experimental results suggest that, for MC/NaCl solution in the presence of HTAB, the salt-induced spherical micelles of HTAB should have formed in bulk solution. For MC solution in the absence of NaCl, no spherical micelles have been formed in bulk solution, though the concentration of HTAB in our experiment is almost one order of magnitude higher than the critical micelle concentration of HTAB in polymer-free solution. In fact, due to adsorption of HTAB on MC chains, the realconcentration of HTAB in bulk solution, is much less than the apparent concentration of HTAB dissolved in MC solution.
Key words:  Sol-gel transition, Methylcellulose, NaCl, HTAB
FundProject:
在NaCl和HTAB共存条件下甲基纤维素溶液凝胶化行为
周珊,杨海洋*,谢永军,李化真,刘光明
摘要:
利用流变仪研究了甲基纤维素(MC)溶液在NaCl、十六烷基三甲基溴化铵(HTAB)以及两者共存下MC溶液的凝胶化行为,发现其凝胶化温度随着NaCl浓度的增加而下降,随着HTAB浓度的增加而上升;但是MC/NaCl的凝胶化温度保持不变,与HTAB浓度 无关,而MC/HTAB溶液的凝胶化温度则随着NaCl浓度的增加而下降.以上的实验结果表明,在NaCl存在下,HTAB将被诱导形成胶束,因此MC/NaCl的凝胶化温度保持不变;反之,当NaCl不存在时,HTAB将优先吸附到MC上而不会在溶液中形成胶束,尽管其浓度
关键词:  凝胶化转变,甲基纤维素,NaCl,十六烷基三甲基溴化铵
DOI:10.1088/1674-0068/24/04/489-496
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