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Influence of Chemical Effect on the Kβ/Kα Intensity Ratios and KβEnergy Shift of Co, Ni, Cu, and Zn Complexes
G.Apaydina,V.AylikCia*,Z.Biyiklioglu,E.Tirasoglu,H.Kantekinb
Author NameAffiliationE-mail
G.Apaydina Department of Physics, Faculty of Arts and Sciences, Karadeniz Technical University, Trabzon 61080, Turkey  
V.AylikCia* Department of Physics, Faculty of Arts and Sciences, Karadeniz Technical University, Trabzon 61080, Turkey v_aylikci@ktu.edu.tr 
Z.Biyiklioglu Department of Chemistry, Faculty of Arts and Sciences, Karadeniz Technical University, Trabzon 61080, Turkey  
E.Tirasoglu Department of Physics, Faculty of Arts and Sciences, Karadeniz Technical University, Trabzon 61080, Turkey  
H.Kantekinb Department of Chemistry, Faculty of Arts and Sciences, Karadeniz Technical University, Trabzon 61080, Turkey  
Abstract:
Chemical effects on the Kβ/Kα intensity ratios and ¢E energy differences for Co, Ni, Cu, and Zn complexes were investigated. The samples were excited by 59.5 keV γ-rays from a 241Am annular radioactive source. K X-rays emitted by samples were counted by an Ultra-LEGe detector with a resolution of 150 eV at 5.9 keV. We observed the effects of different ligands on the Kβ/Kα intensity ratios and ⊿E energy differences for Co, Ni, Cu, and Zn complexes. We tried to investigate chemical effects on central atoms using the behaviors of different ligands in these complexes. The experimental values of Kβ/Kα were compared with the theoretical and other experimental values of pure Co, Ni, Cu, and Zn.
Key words:  Chemical effect, K intensity ratio,⊿E energy difference, Ultra-LEGe detector, 241Am annular radioactive source
FundProject:
Influence of Chemical Effect on the Kβ/Kα Intensity Ratios and KβEnergy Shift of Co, Ni, Cu, and Zn Complexes
G.Apaydina,V.AylikCia*,Z.Biyiklioglu,E.Tirasoglu,H.Kantekinb
摘要:
报导了钴、镍、铜、锌络合物中的化学效应对Kβ/Kα强度比和Kβ能量位移的影响. 实验样品用241Am环状放射源发出的能量为59.5 keV的γ射线激发. 对样品发射的K段X射线进行检测的检测器在5.9 keV处的分辨率为150 eV. 观察了不同配体对钴、镍、铜、锌络合物的Kβ/Kα强度比和Kβ能量转移的影响,并试图解释这些配体的性质对中心原子产生的化学效应. 对实验得到的Kβ/Kα强度比数据,理论计算获得的Kβ/Kα强度比数据及其它实验得到的纯钴、镍、铜、锌的Kβ/Kα强度比数据进行了比较.
关键词:  化学效应,K线强度比, 能量偏移,Ultra-LEGe检测器,241Am环状辐射源
DOI:10.1088/1674-0068/21/06/591-595
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