%0 Journal Article
%T Isotopic Effects on Stereodynamics for Ca+HCl, Ca+DCl, and Ca+TCl Reactions
%A Li zhi Wang
%A Chuan lu Yang
%A Jing juan Liang
%A Jing Xiao
%A Qing gang Zhang
%J Chinese Journal Of Chemical Physics
%@ 1003-7713
%V 24
%N 6
%D 2011
%P 686-690
%K Isotopic effect, Stereodynamics, Quasi-classical trajectory, Vector correlation
%X The vector correlations in Ca+HCl, Ca+DCl, and Ca+TCl reactions have been investigated by means of the quasi-classical trajectory calculations on PES constructed by means of multireference configuration interaction. The distributions of P(θr), P(Φr) and the PDDCSs of (2π/σ)(dσ_{00}/dω_{t}), (2π/σ)(dσ_{20}/dω_{t}), (2π/σ)(dσ_{22+}/dω_{t}), (2π/σ)(dσ_{21-}/dω_{t}) have been calculated based on the surface. The remarkable isotopic effects in the reactions are observed, and the mechanism which may be ascribed to different mass factors is discussed.
%R 10.1088/1674-0068/24/06/686-690
%U http://cjcp.ustc.edu.cn/hxwlxb_en/ch/reader/view_abstract.aspx
%1 JIS Version 3.0.0