Xin-hua Gao, Qing-xiang Ma, Tian-sheng Zhao, Jun Bao, Noritatsu Tsubaki. Recent Advances in Multifunctional Capsule Catalysts in Heterogeneous Catalysis†[J]. Chinese Journal of Chemical Physics , 2018, 31(4): 393-403. doi: 10.1063/1674-0068/31/cjcp1805129
Citation: Xin-hua Gao, Qing-xiang Ma, Tian-sheng Zhao, Jun Bao, Noritatsu Tsubaki. Recent Advances in Multifunctional Capsule Catalysts in Heterogeneous Catalysis[J]. Chinese Journal of Chemical Physics , 2018, 31(4): 393-403. doi: 10.1063/1674-0068/31/cjcp1805129

Recent Advances in Multifunctional Capsule Catalysts in Heterogeneous Catalysis

doi: 10.1063/1674-0068/31/cjcp1805129
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  • Author Bio:

    Noritatsu Tsubaki obtained his B.S. degree in Chemical Physics from USTC in 1987 and received his Ph.D. degree from the University of Tokyo in 1995. He then worked at the University of Tokyo and was promoted to an associate professor in 1999. In 2001, he moved to the University of Toyama as a professor of energy and resources engineering chair in the school of engineering. In 2007, he became a professor of catalysis, energy and material engineering chair of the school of engineering, University of Toyama. His research areas include catalysis, chemical engineering, reaction engineering, nanomaterials, energy from biomass, natural gas, coal, petroleum to sunlight, and membrane sciences. He received Noguchi Memorial Prize for Young Researcher from Japan Petroleum Institute (JPI) in 1998, Progress Prize from Japan Institute of Energy (JIE) in 2000, JSPS Prize from Japan Society for Promotion of Science (JSPS) in 2007. He has published 550 papers, 90 patents and 10 book chapters

  • Corresponding author: Noritatsu Tsubaki, E-mail:tsubaki@eng.u-toyama.ac.jp
  • Received Date: 2018-05-31
  • Accepted Date: 2018-06-14
  • Publish Date: 2018-08-27
  • Capsule catalysts composed of pre-shaped core catalysts and layer zeolites have been widely used in the tandem reactions where multiple continuous reactions are combined into one process. They show excellent catalytic performance in heterogeneous catalysis, including the direct synthesis of middle isoparaffins or dimethyl ether from syngas, as compared to the conventional hybrid catalysts. The present review highlights the recent development in the design of capsule catalysts and their catalytic applications in heterogeneous catalysis. The capsule catalyst preparation methods are introduced in detail, such as hydrothermal synthesis method, dual-layer method, physically adhesive method and single crystal crystallization method. Furthermore, several new applications of capsule catalysts in heterogeneous catalytic processes are presented such as in the direct synthesis of liquefied petroleum gas from syngas, the direct synthesis of para-xylene from syngas and methane dehydroaromatization. In addition, the development in the design of multifunctional capsule catalysts is discussed, which makes the capsule catalyst not just a simple combination of two different catalysts, but has some special functions such as changing the surface hydrophobic or acid properties of the core catalysts. Finally, the future perspectives of the design and applications of capsule catalysts in heterogeneous catalysis are provided.

     

  • Part of the special issue for celebration of "the 60th Anniversary of University of Science and Technology of China and the 30th Anniversary of Chinese Journal of Chemical Physics"
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