Qin-qin Yuan, Zheng Yang, Ren-zhong Li, Wesley J. Transue, Zhi-peng Li, Ling Jiang, Niranjan Govind, Christopher C. Cummins, Xue-Bin Wang. Magnetic-Bottle and Velocity-Map Imaging Photoelectron Spectroscopy of APS- (A=C14H10 or Anthracene): Electron Structure, Spin-Orbit Coupling of APS·, and Dipole-Bound State of APS-[J]. Chinese Journal of Chemical Physics , 2018, 31(4): 463-470. doi: 10.1063/1674-0068/31/cjcp1805114
Citation: Qin-qin Yuan, Zheng Yang, Ren-zhong Li, Wesley J. Transue, Zhi-peng Li, Ling Jiang, Niranjan Govind, Christopher C. Cummins, Xue-Bin Wang. Magnetic-Bottle and Velocity-Map Imaging Photoelectron Spectroscopy of APS- (A=C14H10 or Anthracene): Electron Structure, Spin-Orbit Coupling of APS·, and Dipole-Bound State of APS-[J]. Chinese Journal of Chemical Physics , 2018, 31(4): 463-470. doi: 10.1063/1674-0068/31/cjcp1805114

Magnetic-Bottle and Velocity-Map Imaging Photoelectron Spectroscopy of APS- (A=C14H10 or Anthracene): Electron Structure, Spin-Orbit Coupling of APS·, and Dipole-Bound State of APS-

doi: 10.1063/1674-0068/31/cjcp1805114
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  • Author Bio:

    Xue-Bin Wang received his B.S. in Chemical Physics from University of Science and Technology of China (1988) and his Ph.D in Physical Chemistry from the Institute of Chemistry, Chinese Academy of Sciences (1995) under the supervision of Qi-he Zhu. He worked as a visiting graduate student under the guidance of R. D. Levine from 1993 to 1995 in Hebrew University of Jerusalem. He Joined R. Bersohn's group in 1995 at Columbia University, and L. S. Wang's group in 1997 at PNNL/Washington State University as a postdoctoral Research associate. He worked at PNNLAVashington State University as a research scientist and an associate research professor from 2000 to 2011. He formally joined PNNL in 2011 and is currently a senior research scientist in the Physical Sciences Division at PNNL. He was elected to be a Fellow of the American Physical Society (APS) in 2016. His scientific interests focus on cluster model study of condensed phase chemistry and phenomena via combined photoelectron spectroscopy and theoretical approach

  • Corresponding author: Christopher C. Cummins, E-mail:xuebin.wang@pnnl.gov; Xue-Bin Wang, E-mail:ccummins@mit.edu
  • Received Date: 2018-05-24
  • Accepted Date: 2018-06-07
  • Publish Date: 2018-08-27
  • Gaseous dibenzo-7-phosphanorbornadiene P-sulfide anions APS-(A=C14H10 or anthracene) were generated via electrospray ionization, and characterized by magnetic-bottle photoelectron spectroscopy, velocity-map imaging (VMI) photoelectron spectroscopy, and quantum chemical calculations. The electron affinity (EA) and spin-orbit (SO) splitting of the APS· radical are determined from the photoelectron spectra and Franck-Condon factor simulations to be EA=(2.62±0.05) eV and SO splitting=(43±7) meV. VMI photoelectron images show strong and sharp peaks near the detachment threshold with an identical electron kinetic energy (eKE) of 17.9 meV at three different detachment wavelengths, which are therefore assigned to autodetachment from dipole-bound anion states. The B3LYP/6-31++G(d, p) calculations indicate APS· has a dipole moment of 3.31 Debye, large enough to support a dipole-bound electron.

     

  • Part of the special issue for celebration of "the 60th Anniversary of University of Science and Technology of China and the 30th Anniversary of Chinese Journal of Chemical Physics"
    Visiting students supported via PNNL alternate sponsored fellowship program
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