Rui Wang, Xin-yu Huang, Chun-feng Zhang, Xiao-yong Wang, Min Xiao. Coherent Exciton-Phonon Coupling in CdSe/ZnS Nanocrystals Studied by Two-Dimensional Electronic Spectroscopy[J]. Chinese Journal of Chemical Physics , 2017, 30(6): 637-642. doi: 10.1063/1674-0068/30/cjcp1711222
Citation: Rui Wang, Xin-yu Huang, Chun-feng Zhang, Xiao-yong Wang, Min Xiao. Coherent Exciton-Phonon Coupling in CdSe/ZnS Nanocrystals Studied by Two-Dimensional Electronic Spectroscopy[J]. Chinese Journal of Chemical Physics , 2017, 30(6): 637-642. doi: 10.1063/1674-0068/30/cjcp1711222

Coherent Exciton-Phonon Coupling in CdSe/ZnS Nanocrystals Studied by Two-Dimensional Electronic Spectroscopy

doi: 10.1063/1674-0068/30/cjcp1711222
  • Received Date: 2017-11-15
  • Rev Recd Date: 2017-12-07
  • Coherent exciton-phonon coupling in CdSe/ZnS nanocrystals have been investigated by temperature-dependent two-dimensional electronic spectroscopy (2DES) measurements. Benefiting from the ability of 2DES to dissect assembles in nanocrystal films, we have clearly identified experimental evidences of coherent coupling between exciton and phonon in CdSe/ZnS nanocrystals. In time domain, 2DES signals of excitonic transitions beat at a frequency resonant to a longitudinal optical phonon mode; in energy domain, phonon side bands are distinct at both Stokes and anti-Stokes sides. When temperature increases, phonon-induced exciton dephasing is observed with dramatic broadening of homogeneous linewidth. The results suggest exciton-phonon coupling is essential in elucidating the quantum dynamics of excitonic transitions in semiconductor nanocrystals.

     

  • loading
  • [1]
    V. I. Klimov, Nanocrystal Semiconductor Nanocrystals, Boca Raton:CRC Press, (2010).
    [2]
    A. P. Alivisatos, Science 271, 933(1996).
    [3]
    N. Tessler, V. Medvedev, M. Kazes, S. H. Kan, and U. Banin, Science 295, 1506(2002).
    [4]
    V. L. Colvin, M. C. Schlamp, and A. P. Alivisatos, Nature 370, 354(1994).
    [5]
    X. Dai, Z. Zhang, Y. Jin, Y. Niu, H. Cao, X. Liang, L. Chen, J. Wang, and X. Peng, Nature 515, 96(2014).
    [6]
    F. Fan, O. Voznyy, R. P. Sabatini, K. T. Bicanic, M. M. Adachi, J. R. McBride, K. R. Reid, Y. S. Park, X. Li, A. Jain, R. Quintero-Bermudez, M. Saravanapavanantham, M. Liu, M. Korkusinski, P. Hawrylak, V. I. Klimov, S. J. Rosenthal, S. Hoogland, and E. H. Sargent, Nature 544, 75(2017).
    [7]
    V. I. Klimov, S. A. Ivanov, J. Nanda, M. Achermann, I. Bezel, J. A. McGuire, and A. Piryatinski, Nature 447, 441(2007).
    [8]
    G. Konstantatos and E. H. Sargent, Nature Nanotechnol. 5, 391(2010).
    [9]
    V. Sukhovatkin, S. Hinds, L. Brzozowski, and E. H. Sargent, Science 324, 1542(2009).
    [10]
    N. Somaschi, V. Giesz, L. De Santis, J. C. Loredo, M. P. Almeida, G. Hornecker, S. L. Portalupi, T. Grange, C. Antón, J. Demory, C. Gómez, I. Sagnes, N. D. Lanzillotti-Kimura, A. Lemáıtre, A. Auffeves, A. G. White, L. Lanco, and P. Senellart, Nature Photon. 10, 340(2016).
    [11]
    P. Michler, A. Imamoglu, M. D. Mason, P. J. Carson, G. F. Strouse, and S. K. Buratto, Nature 406, 968(2000).
    [12]
    C. Lin, K. Gong, D. F. Kelley, and A. M. Kelley, J. Phys. Chem. C 119, 7491(2015).
    [13]
    S. Dong, D. Trivedi, S. Chakrabortty, T. Kobayashi, Y. Chan, O. V. Prezhdo, and Z. H. Loh, Nano Lett. 15, 6875(2015).
    [14]
    T. A. Gellen, J. Lem, and D. B. Turner, Nano Lett. 17, 2809(2017).
    [15]
    G. B. Griffin, S. Ithurria, D. S. Dolzhnikov, A. Linkin, D. V. Talapin, and G. S. Engel, J. Chem. Phys. 138, 014705(2013).
    [16]
    B. Mahler, P. Spinicelli, S. Buil, X. Quelin, J. P. Hermier, and B. Dubertret, Nature Mater. 7, 659(2008).
    [17]
    Y. Chen, J. Vela, H. Htoon, J. L. Casson, D. J. Werder, D. A. Bussian, V. I. Klimov, and J. A. Hollingsworth, J. Am. Chem. Soc. 130, 5026(2007).
    [18]
    J. R. Caram, H. Zheng, P. D. Dahlberg, B. S. Rolczynski, G. B. Griffin, A. F. Fidler, D. S. Dolzhnikov, D. V. Talapin, and G. S. Engel, J Phys. Chem. Lett. 5, 196(2014).
    [19]
    E. Cassette, J. C. Dean, and G. D. Scholes, Small 12, 2234(2016).
    [20]
    F. V. de A. Camargo, L. Grimmelsmann, H. L. Anderson, S. R. Meech, and I. A. Heisler, Phys. Rev. Lett. 118, 033001(2017).
    [21]
    E. Harel, S. M. Rupich, R. D. Schaller, D. V. Talapin, and G. S. Engel, Phys. Rev. B 86, 075412(2012).
    [22]
    E. Cassette, R. D. Pensack, B. Mahler, and G. D. Scholes, Nature Commun. 6, 6086(2015).
    [23]
    N. Lenngren, M. A. Abdellah, K. Zheng, M. J. AlMarri, D. Zigmantas, K. Zidek, and T. Pullerits, Phys. Chem. Chem. Phys. 18, 26199(2016).
    [24]
    S. T. Cundiff and S. Mukamel, Phys. Today 66, 44(2013).
    [25]
    S. Pal, P. Nijjar, T. Frauenheim, and O. V. Prezhdo, Nano Lett. 17, 2389(2017).
    [26]
    B. Sun, D. B. Almeida, R. Singh, G. M. Diederich, M. E. Siemens, L. A. Padilha, W. K. Bae, J. M. Pietryga, V. I. Klimov, and S. T. Cundiff, in 2015 Conference on Lasers and Electro-Optics (2015).
    [27]
    W. Zhu, R. Wang, C. Zhang, G. Wang, Y. Liu, W. Zhao, X. Dai, X. Wang, G. Cerullo, S. Cundiff, and M. Xiao, Opt. Express 25, 21115(2017).
    [28]
    A. D. Bristow, D. Karaiskaj, X. Dai, T. Zhang, C. Carlsson, K. R. Hagen, R. Jimenez, and S. T. Cundiff, Rev. Sci. Instr. 80, 073108(2009).
    [29]
    V. I. Klimov, Ann. Rev. Phys. Chem. 58, 635(2007).
    [30]
    D. M. Sagar, R. R. Cooney, S. L. Sewall, E. A. Dias, M. M. Barsan, I. S. Butler, and P. Kambhampati, Phys. Rev. B 77, 235321(2008).
    [31]
    G. Moody, C. Kavir Dass, K. Hao, C. H. Chen, L. J. Li, A. Singh, K. Tran, G. Clark, X. Xu, G. Berghauser, E. Malic, A. Knorr, and X. Li, Nature Commun. 6, 8315(2015).
    [32]
    M. E. Siemens, G. Moody, H. Li, A. D. Bristow, and S. T. Cundiff, Opt. Express 18, 17699(2010).
    [33]
    J. D. Bell, R. Conrad, and M. E. Siemens, Opt. Lett. 40, 1157(2015).
    [34]
    L. Schultheis, A. Honold, J. Kuhl, K. Köhler, and C. W. Tu, Phys. Rev. B 34, 9027(1986).
    [35]
    A. Honold, L. Schultheis, J. Kuhl, and C. W. Tu, Phys. Rev. B 40, 6442(1989).
    [36]
    H. P. Wagner, A. Schätz, and R. Maier, Phys. Rev. B 56, 12581(1997).
    [37]
    I. Calizo, A. A. Balandin, W. Bao, F. Miao, and C. N. Lau, Nano Lett. 7, 2645(2007).
    [38]
    S. Sahoo, A. P. S. Gaur, M. Ahmadi, M. J. F. Guinel, and R. S. Katiyar, J. Phys. Chem. C 117, 9042(2013).
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (1111) PDF downloads(503) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return