Direct Synthesis of Monodisperse Hollow Molecularly Imprinted Polymers Based on Unfunctionalized SiO<sub>2</sub> for the Recognition of Bisphenol A

Shao-min Liu; Meng-xing Wei; Xin Fu; Xue-bin Zhang

doi:10.1063/1674-0068/31/cjcp1708164

Article Contents

Article Navigation > Chinese Journal of Chemical Physics > 2018 > 31(2): 229-237

Shao-min Liu, Meng-xing Wei, Xin Fu, Xue-bin Zhang. Direct Synthesis of Monodisperse Hollow Molecularly Imprinted Polymers Based on Unfunctionalized SiO2 for the Recognition of Bisphenol A[J]. Chinese Journal of Chemical Physics , 2018, 31(2): 229-237. doi: 10.1063/1674-0068/31/cjcp1708164

Citation:

Shao-min Liu, Meng-xing Wei, Xin Fu, Xue-bin Zhang. Direct Synthesis of Monodisperse Hollow Molecularly Imprinted Polymers Based on Unfunctionalized SiO₂ for the Recognition of Bisphenol A[J]. Chinese Journal of Chemical Physics , 2018, 31(2): 229-237. doi: 10.1063/1674-0068/31/cjcp1708164

Direct Synthesis of Monodisperse Hollow Molecularly Imprinted Polymers Based on Unfunctionalized SiO₂ for the Recognition of Bisphenol A

doi: 10.1063/1674-0068/31/cjcp1708164

Department of Chemistry, University of Science and Technology of China, Hefei 230026, China

Received Date: 2017-08-29
Rev Recd Date: 2017-11-27

Abstract

A novel and effective approach was developed to synthesize monodisperse hollow molecularly imprinted polymers (MHMIPs) with unfunctionalized SiO₂ spheres in a mixture of toluene and CH₃CN.The factors that affected the synthesis of MHMIPs were systematically investigated.It was determined that a suitable ratio of toluene to CH₃CN and the use of a functional monomer that can generate double H-bonding interactions were the critical factors to obtain MHMIPs with high uniformity and monodispersion.The obtained MHMIPs exhibited a fast adsorption rate and high adsorption capacity (270 μmol/g) for bisphenol A.As the shell thickness increased from 90 nm to 130 nm,the binding capacity of the imprinted shells decreased gradually.The relative selectivity coefficients of MHMIPs for tetra-bromobisphenol A (TBBPA),phenol and p-tert-butylphenol (PTBP) were calculated as 1.53,1.83 and 1.90,respectively.These findings indicate that MHMIPs have good adsorption performances and suggest applications in the selective removal or sensitive analysis of bisphenol A.
- Hollow molecularly imprint,
- Molecular recognition,
- Nanostructured polymers,
- Bisphenol A

References

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[12]	H. Xiang, M. Peng, H. Li, S. Peng, and S. Shi, J. Pharm. Biomed. Anal. 133, 75(2017).
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[14]	S. R. Carter and S. Rismmer, Adv. Funct. Mater. 14, 553(2014).
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[33]	N. Griffete, H. Li, A. Lamouri, C. Redeuilh, K. Chen, C. Z. Dong, S. Nowak, S. Ammar, and C. Mangeney, J. Mater. Chem. 22, 1807(2012).
[34]	H. Zhou, Y. P. Xu, H. W. Tong, Y. X. Liu, F. Han, X. Y. Yan, and S. M. Liu, J. Appl. Polym. Sci. 128, 3846(2013).
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[39]	B. Peng, E. Wee, A. Imhof, and A. Blaaderen, Langmuir 28, 6776(2012).
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Direct Synthesis of Monodisperse Hollow Molecularly Imprinted Polymers Based on Unfunctionalized SiO₂ for the Recognition of Bisphenol A

Department of Chemistry, University of Science and Technology of China, Hefei 230026, China

Received Date: 2017-08-29

Rev Recd Date: 2017-11-27

Key words:

Abstract: A novel and effective approach was developed to synthesize monodisperse hollow molecularly imprinted polymers (MHMIPs) with unfunctionalized SiO₂ spheres in a mixture of toluene and CH₃CN.The factors that affected the synthesis of MHMIPs were systematically investigated.It was determined that a suitable ratio of toluene to CH₃CN and the use of a functional monomer that can generate double H-bonding interactions were the critical factors to obtain MHMIPs with high uniformity and monodispersion.The obtained MHMIPs exhibited a fast adsorption rate and high adsorption capacity (270 μmol/g) for bisphenol A.As the shell thickness increased from 90 nm to 130 nm,the binding capacity of the imprinted shells decreased gradually.The relative selectivity coefficients of MHMIPs for tetra-bromobisphenol A (TBBPA),phenol and p-tert-butylphenol (PTBP) were calculated as 1.53,1.83 and 1.90,respectively.These findings indicate that MHMIPs have good adsorption performances and suggest applications in the selective removal or sensitive analysis of bisphenol A.

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Reference (47)

[1]	T. Greibrokk, J. SEP. SCI. 39815(2016).
[2]	K. Graniczkowska, M. Putz, F. M. Hauser, S. De Saeger, and N. V. Beloglazova, Biosens. Bioelectron 92, 741(2017).
[3]	S. A. Zaidi, Drug Deliv. 23, 2262(2016).
[4]	D. J. Liu and M. Ulbricht, RSC Adv. 7, 11012(2017).
[5]	C. H. Lu, W. H. Zhou, B. Han, H. H. Yang, X. Chen, and X. R. Wang, Anal. Chem. 79, 5457(2007).
[6]	Z. D. Zhang, S. J. Zheng, J. Yang, W. M. Wang, B. Z. Liu, and X. L. Zhu, Chin. J. Chem. Phys. 26, 361(2013).
[7]	L. X. Chen, S. F. Xu, and J. H. Li, Chem. Soc. Rev. 40, 2922(2011).
[8]	P. P. Tang, J. B. Cai, and Q. D. Su, Chin. J. Chem. Phys. 23, 195(2010).
[9]	X. Deng, C. Chen, J. Xie, C. Cai, and X. Chen, RSC Adv. 6, 43223(2016).
[10]	M. A. Golsefidia, Z. Eśhaghia, and A. Sarafraz-Yazdi, J. Chromatogr. A 1229, 24(2012).
[11]	Z. Zhang, S. F. Xu, J. H. Li, H. Xiong, H. L. Peng, and L. X. Chen, J. Agric. Food Chem. 60, 180(2012).
[12]	H. Xiang, M. Peng, H. Li, S. Peng, and S. Shi, J. Pharm. Biomed. Anal. 133, 75(2017).
[13]	D. Fan, H. Li, S. Shi, and X. Chen, J. Chromatogr.A 1470, 27(2016).
[14]	S. R. Carter and S. Rismmer, Adv. Funct. Mater. 14, 553(2014).
[15]	Y. Y. Zhao, Y. X. Ma, H. Li, and L. Y. Wang, Anal. Chem. 84, 386(2012).
[16]	C. H. Lu, Y. Wang, Y. Li, H. H. Yang, X. Chen, and X. R. Wang, J. Mater. Chem. 19, 1077(2009).
[17]	K. Qian, G. Z. Fang, and S. Wang, Chem. Commun. 47, 10118(2011).
[18]	D. M. Gao, Z. P. Zhang, M. H. Wu, C. G. Xie, G. J. Guan, and D. P. Wang, J. Am. Chem. Soc. 129, 7859(2007).
[19]	J. X. Liu, H. Chen, Z. Lin, and J. M. Lin, Anal. Chem. 82, 7380(2010).
[20]	M. Q. He, M. J. Meng, J. C. Wan, J. He, and Y. S. Yan, Polym. Bull. 68, 1039(2012).
[21]	W. Luo, L. Zhu, C. Yu, H. Tang, H. Yu, X. Li, and X. Zhang, Anal. Chim. Acta. 618, 147(2008).
[22]	W. H. Zhao, N. Sheng, R. Zhu, F. D. Wei, Z. Cai, M. J. Zhai, S. H. Du, and Q. Hu, J. Hazard. Mater. 179, 223(2010).
[23]	C. Gonzato, M. Courty, P. Pasetto, and K. Haupt, Adv. Funct. Mater. 21, 3947(2011).
[24]	M. M. Titirici and B. Sellergren, Chem. Mater. 18, 1773(2006).
[25]	C. Sulitzky, B. Rückert, A. J. Hall, F. Lanza, K. Unger, and B. Sellergren, Macromolecules 35, 79(2002).
[26]	C. H. Lu, W. H. Zhou, B. Han, H. H. Yang, X. Chen, and X. R. Wang, Anal. Chem. 79, 5457(2007).
[27]	K. Wybránska, W. Niemiec, K. Szczubiazka, M. Nowakowska, and Y. Morishima, Chem. Mater. 22, 5392(2010).
[28]	X. M. Jiang, W. Tian, C. D. Zhao, H. X. Zhang, and M. C. Liu, Talanta 72, 119(2007).
[29]	H. Zou, S. S. Wu, and J. Shen, Chem. Rev. 108, 3893(2008).
[30]	W. Stober, A. Fink, and E. Bohn, J. Colloid Interf. Sci. 26, 62(1968).
[31]	X. B. Zhang, J. Li, B. You, H. W. Tong, G. P. Yong, and S. M. Liu, RSC Adv. 2, 9778(2012).
[32]	Z. Lin, Z. W. Xia, J. N. Zheng, D. Zheng, L. Zhang, H. H. Yang, and G. N. Chen, J. Mater. Chem. 22, 17914(2012).
[33]	N. Griffete, H. Li, A. Lamouri, C. Redeuilh, K. Chen, C. Z. Dong, S. Nowak, S. Ammar, and C. Mangeney, J. Mater. Chem. 22, 1807(2012).
[34]	H. Zhou, Y. P. Xu, H. W. Tong, Y. X. Liu, F. Han, X. Y. Yan, and S. M. Liu, J. Appl. Polym. Sci. 128, 3846(2013).
[35]	T. K. Mandal, M. S. Fleming, and D. R. Walt, Chem. Mater. 12, 3481(2000).
[36]	J. F. Wang, P. A. G. Cormack, D. C. Sherrington, and E. Khoshdel, Angew. Chem. Int. Ed. 42, 5336(2003).
[37]	J. F. Zhou, C. Ma, S. Zhou, P. L. Ma, F. R. Chen, Y. Qi, and H. X. Chen, J. Chromatogr. A 1217, 7478(2010).
[38]	A. J. Paine, W. Luymes, and J. McNulty, Macromolecules 23, 3104(1990).
[39]	B. Peng, E. Wee, A. Imhof, and A. Blaaderen, Langmuir 28, 6776(2012).
[40]	T. R. Zhang, Q. Zhang, J. P. Ge, J. Goebl, M. W. Sun, Y. S. Yan, Y. S. Liu, C. L. Chang, J. H. Guo, and Y. D. Yin, J. Phys. Chem. C 113, 3168(2009).
[41]	Y. F. Shi, H. L. Lv, X. F. Lu, Y. Y. Huang, Y. Zhang, and W. Xue, J. Mater. Chem. 22, 3889(2012).
[42]	G. Y. Liu, X. L. Yang, and Y. M. Wang, Polymer 48, 4385(2007).
[43]	T. S. Deng and F. Marlow, Chem. Mater. 24, 536(2012).
[44]	G. Y. Liu, L. Y. Li, X. L. Yang, and Z. Dai, Polym. Adv. Technol. 19, 1922(2008).
[45]	M. C. Cela-Pérez, M. M. Castro-López, A. Lasagabáster-Latorre, J. M. López-Vilaríno, M. V. González-Rodríguez, and L. F. Barral-Losada, Anal. Chim. Acta 706, 275(2011).
[46]	W. Rao, R. Cai, Y. Yin, F. Long, and Z. Zhang, Talanta 128, 170(2014).
[47]	Y. M. Ren, W. Q. Ma, J. Ma, Q. Wen, J. Wang, and F. B. Zhao, J. Colloid. Interf. Sci. 367, 355(2012).

Direct Synthesis of Monodisperse Hollow Molecularly Imprinted Polymers Based on Unfunctionalized SiO₂ for the Recognition of Bisphenol A

doi: 10.1063/1674-0068/31/cjcp1708164

Abstract

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Direct Synthesis of Monodisperse Hollow Molecularly Imprinted Polymers Based on Unfunctionalized SiO₂ for the Recognition of Bisphenol A

doi: 10.1063/1674-0068/31/cjcp1708164

Department of Chemistry, University of Science and Technology of China, Hefei 230026, China

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Direct Synthesis of Monodisperse Hollow Molecularly Imprinted Polymers Based on Unfunctionalized SiO2 for the Recognition of Bisphenol A

doi: 10.1063/1674-0068/31/cjcp1708164

Abstract

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Direct Synthesis of Monodisperse Hollow Molecularly Imprinted Polymers Based on Unfunctionalized SiO2 for the Recognition of Bisphenol A

doi: 10.1063/1674-0068/31/cjcp1708164

Department of Chemistry, University of Science and Technology of China, Hefei 230026, China

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Direct Synthesis of Monodisperse Hollow Molecularly Imprinted Polymers Based on Unfunctionalized SiO₂ for the Recognition of Bisphenol A

Direct Synthesis of Monodisperse Hollow Molecularly Imprinted Polymers Based on Unfunctionalized SiO₂ for the Recognition of Bisphenol A