Hong-hui Ning, Di Lu, Li-qun Zhou, Meng-huan Chen, Yue Li, Gao-jian Zhou, Wei-wei Peng, Zheng Wang. Bimetallic RuM (M=Co, Ni) Alloy NPs Supported on MIL-110(Al): Synergetic Catalysis in Hydrolytic Dehydrogenation of Ammonia Borane[J]. Chinese Journal of Chemical Physics , 2018, 31(1): 99-110. doi: 10.1063/1674-0068/31/cjcp1707137
Citation: Hong-hui Ning, Di Lu, Li-qun Zhou, Meng-huan Chen, Yue Li, Gao-jian Zhou, Wei-wei Peng, Zheng Wang. Bimetallic RuM (M=Co, Ni) Alloy NPs Supported on MIL-110(Al): Synergetic Catalysis in Hydrolytic Dehydrogenation of Ammonia Borane[J]. Chinese Journal of Chemical Physics , 2018, 31(1): 99-110. doi: 10.1063/1674-0068/31/cjcp1707137

Bimetallic RuM (M=Co, Ni) Alloy NPs Supported on MIL-110(Al): Synergetic Catalysis in Hydrolytic Dehydrogenation of Ammonia Borane

doi: 10.1063/1674-0068/31/cjcp1707137
More Information
  • Corresponding author: Li-qun Zhou, E-mail:zlq@hubu.edu.cn
  • Received Date: 2017-07-06
  • Accepted Date: 2017-10-20
  • Publish Date: 2018-02-27
  • By adjusting various Ru/M (M=Co, Ni) molar ratios, a series of highly dispersed bimetallic RuM alloy nanoparticles (NPs) anchored on MIL-110(Al) have been successfully prepared via a conventional impregnation-reduction method. And they are first used as heterogeneous catalysts for the dehydrogenation reaction of AB at room temperature. The results reveal that the as-prepared Ru1Co1@MIL-110 and Ru1Ni1@MIL-110 exhibit the highest catalytic activities in different RuCo and RuNi molar ratios, respectively. It is worthy of note that the turnover frequency (TOF) values of Ru1Co1@MIL-110 and Ru1Ni1@MIL-110 catalysts reached 488.1 and 417.1 mol H2 min-1 (mol Ru)-1 and the activation energies (Ea) are 31.7 and 36.0 kJ/mol, respectively. The superior catalytic performance is attributed to the bimetallic synergistic action between Ru and M, uniform distribution of metal NPs as well as bi-functional effect between RuM alloy NPs and MIL-110. Moreover, these catalysts exhibit favorable stability after 5 consecutive cycles for the hydrolysis of AB.

     

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  • [1]
    M. J. Katz, Z. J. Brown, Y. J. Colon, P. W. Siu, K. A. Scheidt, R. Q. Snurr, J. T. Hupp, and O. K. Farha, Chem. Commun. 49, 9449 (2013). doi: 10.1039/c3cc46105j
    [2]
    S. T. Gao, W. H. Liu, C. Feng, N. Z. Shang, and C. Wang, Catal. Sci. Technol. 6, 869 (2016). doi: 10.1039/C5CY01190F
    [3]
    D. Lu, G. F. Yu, Y. Li, M. H. Chen, Y. X. Pan, L. Q. Zhou, K. Z. Yang, X. Xiong, P. Wu, and Q. H. Xia, J. Alloys Compd. 694, 662 (2017). doi: 10.1016/j.jallcom.2016.10.055
    [4]
    H. C. J. Zhou and S. Kitagawa, Chem. Soc. Rev. 43, 5415 (2014). doi: 10.1039/C4CS90059F
    [5]
    D. Bradshaw, A. Garai, and J. Huo, Chem. Soc. Rev. 41, 2344 (2012). doi: 10.1039/C1CS15276A
    [6]
    F. G. Cirujano, A. L. Pérez, A. Corma, and F. X. Llabrés i Xamena, ChemCatChem. 5, 538 (2013). doi: 10.1002/cctc.201200878
    [7]
    H. Furukawa, K. E. Cordova, M. O'Kee e, and O. M. Yaghi, Science 341, 1230444 (2013). doi: 10.1126/science.1230444
    [8]
    H. C. Zhou, J. R. Long, and O. M. Yaghi, Chem. Rev. 112, 673 (2012). doi: 10.1021/cr300014x
    [9]
    L. E. Kreno, K. Leong, O. K. Farha, M. Allendorf, R. P. Van Duyne, and J. T. Hupp, Chem. Rev. 112, 1105 (2012). doi: 10.1021/cr200324t
    [10]
    K. Z. Yang, L. Q. Zhou, X. Xiong, M. L. Ye, L. Li, and Q. H. Xia, Microporous Mesoporous Mater. 225, 1 (2016). doi: 10.1016/j.micromeso.2015.12.018
    [11]
    A. K. Adhikari, K. S. Lin, and M. T. Tu, J. Taiwan Inst. Chem. E 63, 463 (2016). doi: 10.1016/j.jtice.2016.02.033
    [12]
    S. Ma and H. C. Zhou, Chem. Commun. 46, 44 (2010). doi: 10.1039/B916295J
    [13]
    N. Cao, T. Liu, J. Su, X. J. Wu, W. Luo, and G. Z. Cheng, New J. Chem. 38, 4032 (2014). doi: 10.1039/C4NJ00739E
    [14]
    A. Aijaz, A. Karkamkar, Y. J. Choi, N. Tsumori, E. Ronnebro, T. Autrey, H. Shioyama, and Q. Xu, J. Am. Chem. Soc. 134, 13926 (2012). doi: 10.1021/ja3043905
    [15]
    T. Truong, G. H. Dang, N. V. Tran, N. T. Truong, D. T. Le, and N. T. S. Phan, J. Mol. Catal. A: Chem. 409, 110 (2015). doi: 10.1016/j.molcata.2015.07.022
    [16]
    L. Chen, H. Li, W. Zhan, Z. Cao, J. Chen, Q. Jiang, Y. Jiang, Z. Xie, Q. Kuang, and L. Zheng, ACS Appl. Mater. Interfaces 8, 31059 (2016). doi: 10.1021/acsami.6b11567
    [17]
    J. Li, Q. L. Zhu, and Q. Xu, Catal. Sci. Technol. 5, 525 (2015). doi: 10.1039/C4CY01049C
    [18]
    M. Wen, Y. Kuwahara, K. Mori, D. Zhang, H. Li, and H. Yamashita, J. Mater. Chem. A 3, 14134 (2015). doi: 10.1039/C5TA02320C
    [19]
    P. Z. Li, K. Aranishi, and Q. Xu, Chem. Commun. 48, 3173 (2012). doi: 10.1039/c2cc17302f
    [20]
    T. Umegaki, S. M. Hui, and Y. Kojima, New J. Chem. 41, 992 (2017). doi: 10.1039/C6NJ03457H
    [21]
    W. Grochala and P. P. Edwards, Chem. Rev. 104, 1283 (2004). doi: 10.1021/cr030691s
    [22]
    G. Y. Fan, X. J. Li, Y. L. Ma, Y. Zhang, J. T. Wu, B. Xu, T. Sun, D. J. Gao, and J. Bi, New J. Chem. 41, 2793 (2017). doi: 10.1039/C6NJ02695H
    [23]
    Ö. Metin, H. Can, K. Dendil, and M. S. Gültekin, J. Colloid Interf. Sci. 498, 378 (2017). doi: 10.1016/j.jcis.2017.03.066
    [24]
    Q. Yao, W. M. Shi, G. Feng, Z. H. Lu, X. L. Zhang, D. Tao, D. J. Kong, and X. S. Chen, J. Power Sources 257, 293 (2014). doi: 10.1016/j.jpowsour.2014.01.122
    [25]
    Y. S. Du, N. Cao, L. Yang, W. Luo, and G. Z. Cheng, New J. Chem. 37, 3035 (2013). doi: 10.1039/c3nj00552f
    [26]
    G. Y. Fan, Q. Q. Liu, D. M. Tang, X. J. Li, J. Bi, and D. J. Gao, Int. J. Hydrogen Energy 41, 1542 (2016). doi: 10.1016/j.ijhydene.2015.10.083
    [27]
    Q. S. Shao, R. C. Bai, Z. Y. Tang, Y. F. Gao, J. L. Sun, and M. S. Ren, Surf. Coat. Technol. 302, 185 (2016). doi: 10.1016/j.surfcoat.2016.05.087
    [28]
    M. Rakap, J. Alloys Comp. 649, 1025 (2015). doi: 10.1016/j.jallcom.2015.07.249
    [29]
    N. Shang, X. Zhou, C. Feng, S. Gao, Q. Wu, and C. Wang, Int. J. Hydrogen Energy 42, 5733 (2017). doi: 10.1016/j.ijhydene.2016.11.192
    [30]
    C. Volkringer, D. Popov, T. Loiseau, N. Guillou, G. Ferey, M. Haouas, F. Taulelle, C. Mellot-Draznieks, M. Burghammer, and C. Riekel, Nat. Mater. 6, 760 (2007). doi: 10.1038/nmat1991
    [31]
    M. Haouas, C. Volkringer, T. Loiseau, G. F erey, and F. Taulelle, Chem. Eur. J. 15, 3139 (2009). doi: 10.1002/chem.v15:13
    [32]
    N. A. Khan, J. S. Lee, J. Jeon, C. H. Jun, and S. H. Jhung, Microporous Mesoporous Mater. 152, 235 (2012). doi: 10.1016/j.micromeso.2011.11.025
    [33]
    S. S. Ding, Q. Yan, H. Jiang, Z. X. Zhong, R. Z. Chen, and W. H. Xing, Chem. Eng. J. 296, 146 (2016). doi: 10.1016/j.cej.2016.03.098
    [34]
    N. Z. Shang, C. Feng, S. T. Gao, and C. Wang, Int. J. Hydrogen Energy 41, 944 (2016). doi: 10.1016/j.ijhydene.2015.10.062
    [35]
    J. D. Cai, Y. Y. Huang, and Y. L. Guo, Appl. Catal. B: Environ. 150, 230 (2014).
    [36]
    D. Liang, J. Gao, J. H. Wang, P. Chen, Y. F. Wei, and Z. Y. Hou, Catal. Commun. 12, 1059 (2011). doi: 10.1016/j.catcom.2011.03.019
    [37]
    N. Cao, K. Hu, W. Luo, and G. Z. Cheng, J. Alloys Compd. 590, 241 (2014). doi: 10.1016/j.jallcom.2013.12.134
    [38]
    X. Xiong, L. Q. Zhou, G. F. Yu, K. Z. Yang, M. L. Ye, and Q. H. Xia, Int. J. Hydrogen Energy 40, 15521 (2015). doi: 10.1016/j.ijhydene.2015.09.095
    [39]
    F. Y. Qiu, L. Li, G. Liu, Y. J. Wang, Y. P. Wang, C. F. An, Y. N. Xu, C. C. Xu, Y. Wang, L. F. Jiao, and H. T. Yuan, Int. J. Hydrogen Energy 38, 3241 (2013). doi: 10.1016/j.ijhydene.2012.12.090
    [40]
    L. Yang, J. Su, X. Y. Meng, W. Luo, and G. Z. Cheng, J. Mater. Chem. A 1, 10016 (2013). doi: 10.1039/c3ta11835e
    [41]
    L. Zhang, L. Q. Zhou, K. Z. Yang, D. D. Gao, C. Huang, Y. F. Chen, F. Zhang, X. Xiong, L. Li, and Q. H. Xia, J. Alloys Compd. 677, 87 (2016). doi: 10.1016/j.jallcom.2016.03.234
    [42]
    N. Cao, J. Su, W. Luo, and G. Z. Cheng, Int. J. Hydrogen Energy 39, 426 (2014). doi: 10.1016/j.ijhydene.2013.10.059
    [43]
    N. Cao, J. Su, W. Luo, and G. Z. Cheng, Catal. Commun. 43, 47 (2014). doi: 10.1016/j.catcom.2013.09.003
    [44]
    Q. Yao, Z. H. Lu, Y. Q. Wang, X. S. Chen, and G. Feng, J. Phys. Chem. C 119, 14167 (2015). doi: 10.1021/acs.jpcc.5b02403
    [45]
    M. N. Timofeeva, V. N. Panchenko, A. A. Abel, N. A. Khan, I. Ahmed, A. B. Ayupov, K. P. Volcho, and S. H. Jhung, J. Catal. 311, 114 (2014). doi: 10.1016/j.jcat.2013.11.006
    [46]
    D. D. Ke, Y. Li, J. Wang, L. Zhang, J. D. Wang, X. Zhao, S. Q. Yang, and S. M. Han, Int. J. Hydrogen Energy 41, 2564 (2016). doi: 10.1016/j.ijhydene.2015.11.142
    [47]
    L. Wen, J. Su, X. J. Wu, P. Cai, W. Luo, and G. Z. Cheng, Int. J. Hydrogen Energy 39, 17129 (2014). doi: 10.1016/j.ijhydene.2014.07.179
    [48]
    Y. Y. Huang, J. D. Cai, and Y. L. Guo, Appl. Catal. B: Environ. 129, 549 (2013). doi: 10.1016/j.apcatb.2012.09.049
    [49]
    Y. Li, Y. Dai, and X. K. Tian, Int. J. Hydrogen Energy 40, 9235 (2015). doi: 10.1016/j.ijhydene.2015.05.172
    [50]
    X. J. Li, C. M. Zeng, and G. Y. Fan, Int. J. Hydrogen Energy 40, 9217 (2015). doi: 10.1016/j.ijhydene.2015.05.168
    [51]
    K. Mori, K. Miyawaki, and H. Yamashita, ACS Catal. 6, 3128 (2016). doi: 10.1021/acscatal.6b00715
    [52]
    X. J. Li, C. M. Zeng, and G. Y. Fan, Int. J. Hydrogen Energy 40, 3883 (2015). doi: 10.1016/j.ijhydene.2015.01.122
    [53]
    C. Du, Q. Ao, N. Cao, L. Yang, W. Luo, and G. Z. Cheng, Int. J. Hydrogen Energy 40, 6180 (2015). doi: 10.1016/j.ijhydene.2015.03.070
    [54]
    Y. R. Fan, X. J. Li, X. C. He, C. M. Zeng, G. Y. Fan, Q. Q. Liu, and D. M. Tang, Int. J. Hydrogen Energy 39, 19982 (2014). doi: 10.1016/j.ijhydene.2014.10.012
    [55]
    L. Wen, Z. Zheng, W. Luo, P. Cai, and G. Z. Cheng, Chin. Chem. Lett. 26, 1345 (2015). doi: 10.1016/j.cclet.2015.06.019
    [56]
    K. Z. Yang, L. Q. Zhou, G. F. Yu, X. Xiong, M. L. Ye, Y. Li, D. Lu, Y. X. Pan, M. H. Chen, L. Zhang, D. D. Gao, Z. Wang, H. Y. Liu, and Q. H. Xia, Int. J. Hydrogen Energy 41, 6300 (2016). doi: 10.1016/j.ijhydene.2016.02.104
    [57]
    S. Akbayrak, M. Kaya, M. Volkan, and S.Özkar, J. Mol. Catal. A: Chem. 394, 253 (2014). doi: 10.1016/j.molcata.2014.07.010
    [58]
    N. Cao, W. Luo, and G. Z. Cheng, Int. J. Hydrogen Energy 38, 11964 (2013). doi: 10.1016/j.ijhydene.2013.06.125
    [59]
    G. P. Rachiero, U. B. Demirci, and P. Miele, Int. J. Hydrogen Energy 36, 7051 (2011). doi: 10.1016/j.ijhydene.2011.03.009
    [60]
    Q. L. Yao, Z. H. Lu, W. Huang, X. S. Chen, and J. Zhu, J. Mater. Chem. A 4, 8579 (2016). doi: 10.1039/C6TA02004F
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