Han-bao Chong, Gui-qi Gao, Guang Li. Selective Oxidation of Aldehyde over Hydroxymethyl Group Catalyzed by Gold Nanoparticles in Aqueous Phase[J]. Chinese Journal of Chemical Physics , 2019, 32(6): 747-752. doi: 10.1063/1674-0068/cjcp1905101
Citation: Han-bao Chong, Gui-qi Gao, Guang Li. Selective Oxidation of Aldehyde over Hydroxymethyl Group Catalyzed by Gold Nanoparticles in Aqueous Phase[J]. Chinese Journal of Chemical Physics , 2019, 32(6): 747-752. doi: 10.1063/1674-0068/cjcp1905101

Selective Oxidation of Aldehyde over Hydroxymethyl Group Catalyzed by Gold Nanoparticles in Aqueous Phase

doi: 10.1063/1674-0068/cjcp1905101
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  • Corresponding author: Guang Li, E-mail: liguang1971@ahu.edu.cn
  • Received Date: 2019-05-20
  • Accepted Date: 2019-08-02
  • Publish Date: 2019-12-27
  • A protocol for selectively oxidizing aldehyde over hydroxymethyl group is developed, using biomass starch protected gold nanoparticles (NPs) as catalyst. The Au NPs show high selectivity that aldehyde is oxidized into carboxylic acid while alcoholic hydroxyl group stays intact in selective oxidation of 4-(hydroxymethyl)-benzaldehyde. The heterogeneous catalysis system is composed of soluble catalysts and insoluble substrate. The gold catalyst is prepared, preserved and applied for catalytic oxidation all in water. After reaction conditions are optimized, H$_2$O$_2$ is found to be the best oxidizing agent with complete conversion. Besides, the gold catalyst displays good versitility for aldehyde derivatives. After reaction completes, organic components are extracted by organic solvent and gold NPs in water are separated and recycled.

     

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