Jie Wang, Ying Xiang, Yi-yuan Ding, Yan-fei Xu, Xiang-hui Kong, Guang-yuan Ma, Chanatip Samart, Ming-yue Ding. Bio-syngas Converting to Liquid Fuels over Co Modified Fe$_{3}$O$_{4}$-MnO$_{2}$ Catalysts[J]. Chinese Journal of Chemical Physics , 2019, 32(6): 721-726. doi: 10.1063/1674-0068/cjcp1904086
Citation: Jie Wang, Ying Xiang, Yi-yuan Ding, Yan-fei Xu, Xiang-hui Kong, Guang-yuan Ma, Chanatip Samart, Ming-yue Ding. Bio-syngas Converting to Liquid Fuels over Co Modified Fe$_{3}$O$_{4}$-MnO$_{2}$ Catalysts[J]. Chinese Journal of Chemical Physics , 2019, 32(6): 721-726. doi: 10.1063/1674-0068/cjcp1904086

Bio-syngas Converting to Liquid Fuels over Co Modified Fe$_{3}$O$_{4}$-MnO$_{2}$ Catalysts

doi: 10.1063/1674-0068/cjcp1904086
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  • Corresponding author: Ming-yue Ding, E-mail: dingmy@whu.edu.cn
  • Received Date: 2019-04-29
  • Accepted Date: 2019-06-24
  • Publish Date: 2019-12-27
  • A bifunctional Co modified Fe$_3$O$_4$-Mn catalyst was prepared for Fischer-Tropsch synthesis (FTS). The influence of Co loading on the synergistic effect of Fe-Co as well as FTS performance over Fe$_1$Co$_x$Mn$_1$ catalysts was studied. Incorporation of Co species into the Fe$_3$O$_4$-Mn catalyst promoted the reduction of iron oxides, increasing iron active sites during FTS. Moreover, the adding of Co species enhanced the electron transfer from Fe to Co metal, which strengthened the synergistic effect of Fe-Co, improving the catalytic performance. The Fe$_1$Co$_x$Mn$_1$ catalyst with higher Co loading promoted further the hydrogenation ability, favoring the shifting of the product distribution towards shorter hydrocarbons. Under optimized conditions of 280 ℃, 2.0 MPa and 3000 h$^{-1}$, the highest yield of liquid fuels was obtained for the Fe$_1$Co$_1$Mn$_1$ catalyst.

     

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