Xi-wen Hou, An-qin Qiao, Chuan-ming Cheng. Vibrational Spectra of Nonrigid Molecule HCP in an Algebraic Model[J]. Chinese Journal of Chemical Physics , 2006, 19(6): 478-480. doi: 10.1360/cjcp2006.19(6).478.3
Citation: Xi-wen Hou, An-qin Qiao, Chuan-ming Cheng. Vibrational Spectra of Nonrigid Molecule HCP in an Algebraic Model[J]. Chinese Journal of Chemical Physics , 2006, 19(6): 478-480. doi: 10.1360/cjcp2006.19(6).478.3

Vibrational Spectra of Nonrigid Molecule HCP in an Algebraic Model

doi: 10.1360/cjcp2006.19(6).478.3
  • Received Date: 2005-11-22
  • An algebraic Hamiltonian for the two coupled nonlinear vibrations of highly excited nonrigid molecule HCP was presented. The Hamiltonian reduces to the conventional one in a limit which was expressed in terms of harmonic oscillator operators. It showed that the algebraic model can better reproduce the data than the conventional model by fitting the observed data of HCP.
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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Vibrational Spectra of Nonrigid Molecule HCP in an Algebraic Model

doi: 10.1360/cjcp2006.19(6).478.3

Abstract: An algebraic Hamiltonian for the two coupled nonlinear vibrations of highly excited nonrigid molecule HCP was presented. The Hamiltonian reduces to the conventional one in a limit which was expressed in terms of harmonic oscillator operators. It showed that the algebraic model can better reproduce the data than the conventional model by fitting the observed data of HCP.

Xi-wen Hou, An-qin Qiao, Chuan-ming Cheng. Vibrational Spectra of Nonrigid Molecule HCP in an Algebraic Model[J]. Chinese Journal of Chemical Physics , 2006, 19(6): 478-480. doi: 10.1360/cjcp2006.19(6).478.3
Citation: Xi-wen Hou, An-qin Qiao, Chuan-ming Cheng. Vibrational Spectra of Nonrigid Molecule HCP in an Algebraic Model[J]. Chinese Journal of Chemical Physics , 2006, 19(6): 478-480. doi: 10.1360/cjcp2006.19(6).478.3

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