Jian Li, Yong-qing Li, Wei-li Wang, Feng-cai Ma. Differential Interference Angle of Collision-induced Rotational Energy Transfer in Na2(A1∑+u , v=8~ b3Π0u, v=14)-Na System[J]. Chinese Journal of Chemical Physics , 2006, 19(6): 469-472. doi: 10.1360/cjcp2006.19(6).469.4
Citation: Jian Li, Yong-qing Li, Wei-li Wang, Feng-cai Ma. Differential Interference Angle of Collision-induced Rotational Energy Transfer in Na2(A1∑+u , v=8~ b3Π0u, v=14)-Na System[J]. Chinese Journal of Chemical Physics , 2006, 19(6): 469-472. doi: 10.1360/cjcp2006.19(6).469.4

Differential Interference Angle of Collision-induced Rotational Energy Transfer in Na2(A1∑+u , v=8~ b3Π0u, v=14)-Na System

doi: 10.1360/cjcp2006.19(6).469.4
Funds:  supported by National Natural ScienceFoundation of China (No.10374040)
  • Received Date: 2005-11-03
  • Here we report calculation of the differential interference angles (including b≤ ρ and b≥ρ ) for singlet-triplet mixed states of Na2(A1∑+u,v=8~b3Π0u,v=14) system in collision with Na, in order to study the collision induced quantum interference on rotational energy transfer in an atom-diatom system. The calculation is based on the first-order Born approximation of time-dependent perturbation theory, and the anisotropic Lennard-Jones interaction potentials are also employed. The relationships between differential interference angle and impact parameter, including collision diameter and velocity, are obtained.
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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Differential Interference Angle of Collision-induced Rotational Energy Transfer in Na2(A1∑+u , v=8~ b3Π0u, v=14)-Na System

doi: 10.1360/cjcp2006.19(6).469.4
Funds:  supported by National Natural ScienceFoundation of China (No.10374040)

Abstract: Here we report calculation of the differential interference angles (including b≤ ρ and b≥ρ ) for singlet-triplet mixed states of Na2(A1∑+u,v=8~b3Π0u,v=14) system in collision with Na, in order to study the collision induced quantum interference on rotational energy transfer in an atom-diatom system. The calculation is based on the first-order Born approximation of time-dependent perturbation theory, and the anisotropic Lennard-Jones interaction potentials are also employed. The relationships between differential interference angle and impact parameter, including collision diameter and velocity, are obtained.

Jian Li, Yong-qing Li, Wei-li Wang, Feng-cai Ma. Differential Interference Angle of Collision-induced Rotational Energy Transfer in Na2(A1∑+u , v=8~ b3Π0u, v=14)-Na System[J]. Chinese Journal of Chemical Physics , 2006, 19(6): 469-472. doi: 10.1360/cjcp2006.19(6).469.4
Citation: Jian Li, Yong-qing Li, Wei-li Wang, Feng-cai Ma. Differential Interference Angle of Collision-induced Rotational Energy Transfer in Na2(A1∑+u , v=8~ b3Π0u, v=14)-Na System[J]. Chinese Journal of Chemical Physics , 2006, 19(6): 469-472. doi: 10.1360/cjcp2006.19(6).469.4

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