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Article Navigation >  Chinese Journal of Chemical Physics  > 2005  >  18(6): 872-876

Ma Jing, Ding Lei, Gu Xuejun, Zheng Haiyang, Fang Li, Zhang Weijun, Yang Rui, Wang Jing, Qi Fei. Photoionization Studies of Chlorobenzene Using Synchrotron Radiation[J]. Chinese Journal of Chemical Physics , 2005, 18(6): 872-876. doi: 10.1088/1674-0068/18/6/872-876
Citation: Ma Jing, Ding Lei, Gu Xuejun, Zheng Haiyang, Fang Li, Zhang Weijun, Yang Rui, Wang Jing, Qi Fei. Photoionization Studies of Chlorobenzene Using Synchrotron Radiation[J]. Chinese Journal of Chemical Physics , 2005, 18(6): 872-876. doi: 10.1088/1674-0068/18/6/872-876
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Photoionization Studies of Chlorobenzene Using Synchrotron Radiation

doi: 10.1088/1674-0068/18/6/872-876
  • 1.

    Laboratory of Environmental Spectroscopy, Anhui Institute of Optics and Fine Mechanics, Chinese Academic of Sciences, Hefei 230031

  • 2.

    National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029

Funds:  Project supported by the National Knowledge Innovation Program from the Chinese Academy of Science.(KJCX2-SW-H08)
  • Received Date: 2004-12-27
  • Photoionization studies of chlorobenzene were performed by using a time-of-flight mass spectrometer (TOF-MS) with vacuum ultraviolet (VUV) photons from the Heifei synchrotron radiation source. The photoionization mass spectrum and the photoionization efficiency (PIE) curves of both parent and fragment ions were measured. The appearance potentials of the major ions were obtained from their PIE curves. From these data, the standard formation enthalpies of C6H5Cl+, C6H+5 and C4H+3 were evaluated, some dissociative energy was derived. We will be able to detect chlorobenzen with SPI-TOFMS and 118.0 nm laser light.
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通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

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Photoionization Studies of Chlorobenzene Using Synchrotron Radiation

doi: 10.1088/1674-0068/18/6/872-876
  • 1. Laboratory of Environmental Spectroscopy, Anhui Institute of Optics and Fine Mechanics, Chinese Academic of Sciences, Hefei 230031
  • 2. National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029
Funds:  Project supported by the National Knowledge Innovation Program from the Chinese Academy of Science.(KJCX2-SW-H08)
  • Received Date: 2004-12-27

Abstract: Photoionization studies of chlorobenzene were performed by using a time-of-flight mass spectrometer (TOF-MS) with vacuum ultraviolet (VUV) photons from the Heifei synchrotron radiation source. The photoionization mass spectrum and the photoionization efficiency (PIE) curves of both parent and fragment ions were measured. The appearance potentials of the major ions were obtained from their PIE curves. From these data, the standard formation enthalpies of C6H5Cl+, C6H+5 and C4H+3 were evaluated, some dissociative energy was derived. We will be able to detect chlorobenzen with SPI-TOFMS and 118.0 nm laser light.

Ma Jing, Ding Lei, Gu Xuejun, Zheng Haiyang, Fang Li, Zhang Weijun, Yang Rui, Wang Jing, Qi Fei. Photoionization Studies of Chlorobenzene Using Synchrotron Radiation[J]. Chinese Journal of Chemical Physics , 2005, 18(6): 872-876. doi: 10.1088/1674-0068/18/6/872-876
Citation: Ma Jing, Ding Lei, Gu Xuejun, Zheng Haiyang, Fang Li, Zhang Weijun, Yang Rui, Wang Jing, Qi Fei. Photoionization Studies of Chlorobenzene Using Synchrotron Radiation[J]. Chinese Journal of Chemical Physics , 2005, 18(6): 872-876. doi: 10.1088/1674-0068/18/6/872-876
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