Liu Ning, Yan Guoqing, Tong Wei. Influence of Gd Doping on Magnetic Behaviour in La0.67Sr0.33CoO3, La0.67Sr0.33MnO3[J]. Chinese Journal of Chemical Physics , 2005, 18(4): 589-593. doi: 10.1088/1674-0068/18/4/589-593
Citation: Liu Ning, Yan Guoqing, Tong Wei. Influence of Gd Doping on Magnetic Behaviour in La0.67Sr0.33CoO3, La0.67Sr0.33MnO3[J]. Chinese Journal of Chemical Physics , 2005, 18(4): 589-593. doi: 10.1088/1674-0068/18/4/589-593

Influence of Gd Doping on Magnetic Behaviour in La0.67Sr0.33CoO3, La0.67Sr0.33MnO3

doi: 10.1088/1674-0068/18/4/589-593
Funds:  Project supported by the National Natural Science Foundation of China (19934003) and the State Key Project of Fundamental Research of China ( 001 CB610604).
  • Received Date: 2004-07-05
  • M~T curves and M~H curves of the systems La0.67Sr0.33CoO3, La0.67Sr0.33MnO3 (x=0.00, 0.05, 0.10, 0.20, 0.30, 0.40, 0.50, 0.60, 0.67) were studied by experiments. Experimental results show that the magnetic structure of La0.67-xGdxSr0.33CoO3 system exhibits the cluster glass state with doping Gd increasing. The M~T curves of samples x>0.10 exhibit a peculiar phenomenon that M value rises sharply at low temperature range. The magnetic structure of La0.67-xGdxSr0.33MnO3 system changes from the longrang ferromagnetic order to the cluster glass state, and antiferromagnetic state. The M~T curves of samples x≥0.50 decline sharply at low temperature range. The different phenomena shown by the two systems come from different coupling function between Gd and Co, Mn and from spin state transition of Co.
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Influence of Gd Doping on Magnetic Behaviour in La0.67Sr0.33CoO3, La0.67Sr0.33MnO3

doi: 10.1088/1674-0068/18/4/589-593
Funds:  Project supported by the National Natural Science Foundation of China (19934003) and the State Key Project of Fundamental Research of China ( 001 CB610604).

Abstract: M~T curves and M~H curves of the systems La0.67Sr0.33CoO3, La0.67Sr0.33MnO3 (x=0.00, 0.05, 0.10, 0.20, 0.30, 0.40, 0.50, 0.60, 0.67) were studied by experiments. Experimental results show that the magnetic structure of La0.67-xGdxSr0.33CoO3 system exhibits the cluster glass state with doping Gd increasing. The M~T curves of samples x>0.10 exhibit a peculiar phenomenon that M value rises sharply at low temperature range. The magnetic structure of La0.67-xGdxSr0.33MnO3 system changes from the longrang ferromagnetic order to the cluster glass state, and antiferromagnetic state. The M~T curves of samples x≥0.50 decline sharply at low temperature range. The different phenomena shown by the two systems come from different coupling function between Gd and Co, Mn and from spin state transition of Co.

Liu Ning, Yan Guoqing, Tong Wei. Influence of Gd Doping on Magnetic Behaviour in La0.67Sr0.33CoO3, La0.67Sr0.33MnO3[J]. Chinese Journal of Chemical Physics , 2005, 18(4): 589-593. doi: 10.1088/1674-0068/18/4/589-593
Citation: Liu Ning, Yan Guoqing, Tong Wei. Influence of Gd Doping on Magnetic Behaviour in La0.67Sr0.33CoO3, La0.67Sr0.33MnO3[J]. Chinese Journal of Chemical Physics , 2005, 18(4): 589-593. doi: 10.1088/1674-0068/18/4/589-593

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