Ding Pei, Liang Erjun, Chao Mingju, Guo Xinyong, Zhang Jingwei. Synthesis of CNx Nanotubes Catalyzed by Ferrocene[J]. Chinese Journal of Chemical Physics , 2005, 18(2): 268-272. doi: 10.1088/1674-0068/18/2/268-272
Citation: Ding Pei, Liang Erjun, Chao Mingju, Guo Xinyong, Zhang Jingwei. Synthesis of CNx Nanotubes Catalyzed by Ferrocene[J]. Chinese Journal of Chemical Physics , 2005, 18(2): 268-272. doi: 10.1088/1674-0068/18/2/268-272

Synthesis of CNx Nanotubes Catalyzed by Ferrocene

doi: 10.1088/1674-0068/18/2/268-272
Funds:  Project supported by the Fund for University Creative Talent of Henan Province (1999-125) and the Youth Science Foundation of Zhengzhou Institute of Aeronautical Industry Management.
  • Received Date: 2004-02-14
  • CNx nanotubes have been synthesized by thermal decomposition of ferrocene/ethylenediamine (Fe(C5H5)2/C2H8N2) mixture using ferrocene as the catalyst at 800~1040℃. Transmission electron microscopy (TEM) and Raman spectroscopic were used to characterize the CNx nantoubes produced at different temperatures, whose yields were also investigated. It is shown that the CNx nanotubes have bamboolike structure, and the average diameter, crystallinity and yields increase with the temperature increasing. X-ray photoelectron spectrum (XPS) revealed the nitrogen incorporation of the CNx nanotubes. The catalysis mechanism of ferrocene in the growth of the CNx nanotubes is also discussed.
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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Synthesis of CNx Nanotubes Catalyzed by Ferrocene

doi: 10.1088/1674-0068/18/2/268-272
Funds:  Project supported by the Fund for University Creative Talent of Henan Province (1999-125) and the Youth Science Foundation of Zhengzhou Institute of Aeronautical Industry Management.

Abstract: CNx nanotubes have been synthesized by thermal decomposition of ferrocene/ethylenediamine (Fe(C5H5)2/C2H8N2) mixture using ferrocene as the catalyst at 800~1040℃. Transmission electron microscopy (TEM) and Raman spectroscopic were used to characterize the CNx nantoubes produced at different temperatures, whose yields were also investigated. It is shown that the CNx nanotubes have bamboolike structure, and the average diameter, crystallinity and yields increase with the temperature increasing. X-ray photoelectron spectrum (XPS) revealed the nitrogen incorporation of the CNx nanotubes. The catalysis mechanism of ferrocene in the growth of the CNx nanotubes is also discussed.

Ding Pei, Liang Erjun, Chao Mingju, Guo Xinyong, Zhang Jingwei. Synthesis of CNx Nanotubes Catalyzed by Ferrocene[J]. Chinese Journal of Chemical Physics , 2005, 18(2): 268-272. doi: 10.1088/1674-0068/18/2/268-272
Citation: Ding Pei, Liang Erjun, Chao Mingju, Guo Xinyong, Zhang Jingwei. Synthesis of CNx Nanotubes Catalyzed by Ferrocene[J]. Chinese Journal of Chemical Physics , 2005, 18(2): 268-272. doi: 10.1088/1674-0068/18/2/268-272

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