Zhu Hejun, Ding Yunjie, Yan Li, Xiong Jianmin, Yin Hongmei, Lü Yuan, Lin Liwu. A New Hydroformylation Catalyst Comprising High Dispersed Metal Particles and Water-soluble Ligands: TPPTS-Rh/SiO2[J]. Chinese Journal of Chemical Physics , 2002, 15(3): 229-232. doi: 10.1088/1674-0068/15/3/229-232
Citation: Zhu Hejun, Ding Yunjie, Yan Li, Xiong Jianmin, Yin Hongmei, Lü Yuan, Lin Liwu. A New Hydroformylation Catalyst Comprising High Dispersed Metal Particles and Water-soluble Ligands: TPPTS-Rh/SiO2[J]. Chinese Journal of Chemical Physics , 2002, 15(3): 229-232. doi: 10.1088/1674-0068/15/3/229-232

A New Hydroformylation Catalyst Comprising High Dispersed Metal Particles and Water-soluble Ligands: TPPTS-Rh/SiO2

doi: 10.1088/1674-0068/15/3/229-232
  • Received Date: 2002-03-25
  • Hydroformylation of 1-hexene over a series of silica supported noble metal catalysts,HRhCO(TPP)3,HRhCO(TPPTS)3/SiO2 and TPPTS-Rh/SiO2 catalyst were investigated. The results show that the selectivity towards aldehydes and the ratio of liner to branched aldehyde( n/b)over Rh-TPPTS / SiO2 catalyst are near to those of HRhCO(TPPTS)3/SiO2,but much higher than to those of Rh/SiO2 . Under the higher pressure of 7.0 MPa,the TOF of aldehydes on Rh-TPPTS / SiO2 catalyst increase greatly up to 0.0692 S-1 . A possible of catalyst model of Ligands containing lone-pair electron tightly chemically connected to the highly dispersed Rh particles and formation of supported aqueous-film heterogeneous catalyst possessing of homogeneous catalytic performance has been tentatively proposed.
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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A New Hydroformylation Catalyst Comprising High Dispersed Metal Particles and Water-soluble Ligands: TPPTS-Rh/SiO2

doi: 10.1088/1674-0068/15/3/229-232

Abstract: Hydroformylation of 1-hexene over a series of silica supported noble metal catalysts,HRhCO(TPP)3,HRhCO(TPPTS)3/SiO2 and TPPTS-Rh/SiO2 catalyst were investigated. The results show that the selectivity towards aldehydes and the ratio of liner to branched aldehyde( n/b)over Rh-TPPTS / SiO2 catalyst are near to those of HRhCO(TPPTS)3/SiO2,but much higher than to those of Rh/SiO2 . Under the higher pressure of 7.0 MPa,the TOF of aldehydes on Rh-TPPTS / SiO2 catalyst increase greatly up to 0.0692 S-1 . A possible of catalyst model of Ligands containing lone-pair electron tightly chemically connected to the highly dispersed Rh particles and formation of supported aqueous-film heterogeneous catalyst possessing of homogeneous catalytic performance has been tentatively proposed.

Zhu Hejun, Ding Yunjie, Yan Li, Xiong Jianmin, Yin Hongmei, Lü Yuan, Lin Liwu. A New Hydroformylation Catalyst Comprising High Dispersed Metal Particles and Water-soluble Ligands: TPPTS-Rh/SiO2[J]. Chinese Journal of Chemical Physics , 2002, 15(3): 229-232. doi: 10.1088/1674-0068/15/3/229-232
Citation: Zhu Hejun, Ding Yunjie, Yan Li, Xiong Jianmin, Yin Hongmei, Lü Yuan, Lin Liwu. A New Hydroformylation Catalyst Comprising High Dispersed Metal Particles and Water-soluble Ligands: TPPTS-Rh/SiO2[J]. Chinese Journal of Chemical Physics , 2002, 15(3): 229-232. doi: 10.1088/1674-0068/15/3/229-232

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