Lin Weiwei, Nan Junyi, Tian Yonghui, Liang Huijian. XPS Study of Competing Doping Behavior of Polyaniline[J]. Chinese Journal of Chemical Physics , 2000, 13(5): 592-598. doi: 10.1088/1674-0068/13/5/592-598
Citation: Lin Weiwei, Nan Junyi, Tian Yonghui, Liang Huijian. XPS Study of Competing Doping Behavior of Polyaniline[J]. Chinese Journal of Chemical Physics , 2000, 13(5): 592-598. doi: 10.1088/1674-0068/13/5/592-598

XPS Study of Competing Doping Behavior of Polyaniline

doi: 10.1088/1674-0068/13/5/592-598
  • Received Date: 1999-11-15
  • Thestructure and protonation levelof conductive polyaniline (PANI) chemicallysynthesized in different reactive systems have been investigated using X-ray photoelectron spectroscopy (XPS). Polyaniline prepared in hydrochloric acid aqueoussolution easily undergoes deprotonation under prolonging exposure to vacuum at 60℃. When polyaniline was prepared by solution of coexistence of sodium dode-cylbenzene sulfonate (SDBS) and hydrochloric acid, two kinds of counterion (DBS-and Cl-) occurred competing doping behavior. The results reveal that DBS-take part in associating with positively charged polyaniline backbone, and that the N1sand S2pXPS core levelspectraare verysimilar to thatof polyani-line doped by dodecylbenzene sulfonate acid (DBSA) alone.Howerer, SDBS-HCl coexisting system is more favorabale than that of DBSA alone.
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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XPS Study of Competing Doping Behavior of Polyaniline

doi: 10.1088/1674-0068/13/5/592-598

Abstract: Thestructure and protonation levelof conductive polyaniline (PANI) chemicallysynthesized in different reactive systems have been investigated using X-ray photoelectron spectroscopy (XPS). Polyaniline prepared in hydrochloric acid aqueoussolution easily undergoes deprotonation under prolonging exposure to vacuum at 60℃. When polyaniline was prepared by solution of coexistence of sodium dode-cylbenzene sulfonate (SDBS) and hydrochloric acid, two kinds of counterion (DBS-and Cl-) occurred competing doping behavior. The results reveal that DBS-take part in associating with positively charged polyaniline backbone, and that the N1sand S2pXPS core levelspectraare verysimilar to thatof polyani-line doped by dodecylbenzene sulfonate acid (DBSA) alone.Howerer, SDBS-HCl coexisting system is more favorabale than that of DBSA alone.

Lin Weiwei, Nan Junyi, Tian Yonghui, Liang Huijian. XPS Study of Competing Doping Behavior of Polyaniline[J]. Chinese Journal of Chemical Physics , 2000, 13(5): 592-598. doi: 10.1088/1674-0068/13/5/592-598
Citation: Lin Weiwei, Nan Junyi, Tian Yonghui, Liang Huijian. XPS Study of Competing Doping Behavior of Polyaniline[J]. Chinese Journal of Chemical Physics , 2000, 13(5): 592-598. doi: 10.1088/1674-0068/13/5/592-598

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