Ning Shi, Qi-ying Liu, Tie-jun Wang, Qi Zhang, Long-long Ma, Chi-liu Cai. Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulosic Biomass in Water-Tetrahydrofuran Media with Sodium Bisulfate[J]. Chinese Journal of Chemical Physics , 2015, 28(5): 650-656. doi: 10.1063/1674-0068/28/cjcp1501008
Citation: Ning Shi, Qi-ying Liu, Tie-jun Wang, Qi Zhang, Long-long Ma, Chi-liu Cai. Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulosic Biomass in Water-Tetrahydrofuran Media with Sodium Bisulfate[J]. Chinese Journal of Chemical Physics , 2015, 28(5): 650-656. doi: 10.1063/1674-0068/28/cjcp1501008

Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulosic Biomass in Water-Tetrahydrofuran Media with Sodium Bisulfate

doi: 10.1063/1674-0068/28/cjcp1501008
  • Received Date: 2015-01-22
  • 5-Hydroxymethylfurfural (HMF) and furfural (FF), two bio-based platform chemicals, were produced from various raw lignocellulosic materials (corncob, corn stover, wheat straw, rice straw and sugarcane bagasse) in a water-tetrahydrofuran media by using NaHSO4 as catalyst. The in fluences of reaction temperature (160-200 oC), reaction time (30-120 min), solvent volume ratio, feedstock concentration (2.4wt%-11.1wt%) and catalyst dosage were studied. The highest HMF and FF yields obtained from corncob were 47mol% and 56mol% under condition of 190 oC, 90 min, 10/1 of THF/H2O. Besides, the lignin in the raw biomass wasalso depolymerized into organosolv lignin.
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulosic Biomass in Water-Tetrahydrofuran Media with Sodium Bisulfate

doi: 10.1063/1674-0068/28/cjcp1501008

Abstract: 5-Hydroxymethylfurfural (HMF) and furfural (FF), two bio-based platform chemicals, were produced from various raw lignocellulosic materials (corncob, corn stover, wheat straw, rice straw and sugarcane bagasse) in a water-tetrahydrofuran media by using NaHSO4 as catalyst. The in fluences of reaction temperature (160-200 oC), reaction time (30-120 min), solvent volume ratio, feedstock concentration (2.4wt%-11.1wt%) and catalyst dosage were studied. The highest HMF and FF yields obtained from corncob were 47mol% and 56mol% under condition of 190 oC, 90 min, 10/1 of THF/H2O. Besides, the lignin in the raw biomass wasalso depolymerized into organosolv lignin.

Ning Shi, Qi-ying Liu, Tie-jun Wang, Qi Zhang, Long-long Ma, Chi-liu Cai. Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulosic Biomass in Water-Tetrahydrofuran Media with Sodium Bisulfate[J]. Chinese Journal of Chemical Physics , 2015, 28(5): 650-656. doi: 10.1063/1674-0068/28/cjcp1501008
Citation: Ning Shi, Qi-ying Liu, Tie-jun Wang, Qi Zhang, Long-long Ma, Chi-liu Cai. Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulosic Biomass in Water-Tetrahydrofuran Media with Sodium Bisulfate[J]. Chinese Journal of Chemical Physics , 2015, 28(5): 650-656. doi: 10.1063/1674-0068/28/cjcp1501008

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