Shi-song Li, Ji-gui Cheng, Xu-cheng Zhang, Yu Wang, Kui Xie. Composite Cathode Based on Redox-Reversible Nb2TiO7 for Direct High-Temperature Steam Electrolysis[J]. Chinese Journal of Chemical Physics , 2015, 28(3): 323-330. doi: 10.1063/1674-0068/28/cjcp1412210
Citation: Shi-song Li, Ji-gui Cheng, Xu-cheng Zhang, Yu Wang, Kui Xie. Composite Cathode Based on Redox-Reversible Nb2TiO7 for Direct High-Temperature Steam Electrolysis[J]. Chinese Journal of Chemical Physics , 2015, 28(3): 323-330. doi: 10.1063/1674-0068/28/cjcp1412210

Composite Cathode Based on Redox-Reversible Nb2TiO7 for Direct High-Temperature Steam Electrolysis

doi: 10.1063/1674-0068/28/cjcp1412210
  • Received Date: 2014-12-18
  • Ni/YSZ fuel electrodes can only operate under strongly reducing conditions for steam electrolysis in an oxide-ion-conducting solid oxide electrolyzer (SOE). In atmosphere with a low content of H2 or without H2, cathodes based on redox-reversible Nb2TiO7 provide a promising alternative. The reversible changes between oxidized Nb2TiO7 and reduced Nb1.33Ti0.67O4 samples are systematically investigated after redox-cycling tests. The conductivities of Nb2TiO7 and reduced Nb1.33Ti0.67O4 are studied as a function of temperature and oxygen partial pressure and correlated with the electrochemical properties of the composite electrodes in a symmetric cell and SOE at 830 oC. Steam electrolysis is then performed using an oxide-ion-conducting SOE based on a Nb1.33Ti0.67O4 composite fuel electrode at 830 oC. The current-voltage and impedance spectroscopy tests demonstrate that the reduction and activation of the fuel electrode is the main process at low voltage; however, the steam electrolysis dominates the entire process at high voltages. The Faradic efficiencies of steam electrolysis reach 98.9% when 3%H2O/Ar/4%H2 is introduced to the fuel electrode and 89% for that with introduction of 3%H2O/Ar.
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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Composite Cathode Based on Redox-Reversible Nb2TiO7 for Direct High-Temperature Steam Electrolysis

doi: 10.1063/1674-0068/28/cjcp1412210

Abstract: Ni/YSZ fuel electrodes can only operate under strongly reducing conditions for steam electrolysis in an oxide-ion-conducting solid oxide electrolyzer (SOE). In atmosphere with a low content of H2 or without H2, cathodes based on redox-reversible Nb2TiO7 provide a promising alternative. The reversible changes between oxidized Nb2TiO7 and reduced Nb1.33Ti0.67O4 samples are systematically investigated after redox-cycling tests. The conductivities of Nb2TiO7 and reduced Nb1.33Ti0.67O4 are studied as a function of temperature and oxygen partial pressure and correlated with the electrochemical properties of the composite electrodes in a symmetric cell and SOE at 830 oC. Steam electrolysis is then performed using an oxide-ion-conducting SOE based on a Nb1.33Ti0.67O4 composite fuel electrode at 830 oC. The current-voltage and impedance spectroscopy tests demonstrate that the reduction and activation of the fuel electrode is the main process at low voltage; however, the steam electrolysis dominates the entire process at high voltages. The Faradic efficiencies of steam electrolysis reach 98.9% when 3%H2O/Ar/4%H2 is introduced to the fuel electrode and 89% for that with introduction of 3%H2O/Ar.

Shi-song Li, Ji-gui Cheng, Xu-cheng Zhang, Yu Wang, Kui Xie. Composite Cathode Based on Redox-Reversible Nb2TiO7 for Direct High-Temperature Steam Electrolysis[J]. Chinese Journal of Chemical Physics , 2015, 28(3): 323-330. doi: 10.1063/1674-0068/28/cjcp1412210
Citation: Shi-song Li, Ji-gui Cheng, Xu-cheng Zhang, Yu Wang, Kui Xie. Composite Cathode Based on Redox-Reversible Nb2TiO7 for Direct High-Temperature Steam Electrolysis[J]. Chinese Journal of Chemical Physics , 2015, 28(3): 323-330. doi: 10.1063/1674-0068/28/cjcp1412210

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