Chun-lin Song, Jian-xin Yi. Influence of CO2 on Oxygen Surface Exchange Kinetics of Mixed-Conducting Ba0.5Sr0.5Co0.8Fe0.2O3−δ Oxide[J]. Chinese Journal of Chemical Physics , 2015, 28(2): 203-205. doi: 10.1063/1674-0068/28/cjcp1412203
Citation: Chun-lin Song, Jian-xin Yi. Influence of CO2 on Oxygen Surface Exchange Kinetics of Mixed-Conducting Ba0.5Sr0.5Co0.8Fe0.2O3−δ Oxide[J]. Chinese Journal of Chemical Physics , 2015, 28(2): 203-205. doi: 10.1063/1674-0068/28/cjcp1412203

Influence of CO2 on Oxygen Surface Exchange Kinetics of Mixed-Conducting Ba0.5Sr0.5Co0.8Fe0.2O3−δ Oxide

doi: 10.1063/1674-0068/28/cjcp1412203
  • Received Date: 2014-12-01
  • The poisoning effect of CO2 on the oxygen surface exchange kinetics of BSCF (Ba0.5Sr0.5Co0.8Fe0.2O3-δ) is investigated with a novel pulse isotopic exchange technique. The surface exchange rate of BSCF severely decreases after in situ exposure to CO2, which is ascribed to carbonate formation on the material surface. The detrimental effect of CO2 starts at a low temperature of 375 oC and concentration as low as 1%, and becomes more pronounced at higher temperatures. Degradation of the surface exchange kinetics is associated with a rapid loss of oxygen permeation performance of BSCF in CO2.
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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Influence of CO2 on Oxygen Surface Exchange Kinetics of Mixed-Conducting Ba0.5Sr0.5Co0.8Fe0.2O3−δ Oxide

doi: 10.1063/1674-0068/28/cjcp1412203

Abstract: The poisoning effect of CO2 on the oxygen surface exchange kinetics of BSCF (Ba0.5Sr0.5Co0.8Fe0.2O3-δ) is investigated with a novel pulse isotopic exchange technique. The surface exchange rate of BSCF severely decreases after in situ exposure to CO2, which is ascribed to carbonate formation on the material surface. The detrimental effect of CO2 starts at a low temperature of 375 oC and concentration as low as 1%, and becomes more pronounced at higher temperatures. Degradation of the surface exchange kinetics is associated with a rapid loss of oxygen permeation performance of BSCF in CO2.

Chun-lin Song, Jian-xin Yi. Influence of CO2 on Oxygen Surface Exchange Kinetics of Mixed-Conducting Ba0.5Sr0.5Co0.8Fe0.2O3−δ Oxide[J]. Chinese Journal of Chemical Physics , 2015, 28(2): 203-205. doi: 10.1063/1674-0068/28/cjcp1412203
Citation: Chun-lin Song, Jian-xin Yi. Influence of CO2 on Oxygen Surface Exchange Kinetics of Mixed-Conducting Ba0.5Sr0.5Co0.8Fe0.2O3−δ Oxide[J]. Chinese Journal of Chemical Physics , 2015, 28(2): 203-205. doi: 10.1063/1674-0068/28/cjcp1412203

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