Zhi-guo Zhang, Zhi-chao Chen, Cui-mei Zhang, Yan-ling Jin, Qun Zhang, Yang Chen, Cun-shun Huang, Xue-ming Yang. Ion-Velocity Map Imaging Study of Photodissociation Dynamics of Acetaldehyde[J]. Chinese Journal of Chemical Physics , 2014, 27(3): 249-255. doi: 10.1063/1674-0068/27/03/249-255
Citation: Zhi-guo Zhang, Zhi-chao Chen, Cui-mei Zhang, Yan-ling Jin, Qun Zhang, Yang Chen, Cun-shun Huang, Xue-ming Yang. Ion-Velocity Map Imaging Study of Photodissociation Dynamics of Acetaldehyde[J]. Chinese Journal of Chemical Physics , 2014, 27(3): 249-255. doi: 10.1063/1674-0068/27/03/249-255

Ion-Velocity Map Imaging Study of Photodissociation Dynamics of Acetaldehyde

doi: 10.1063/1674-0068/27/03/249-255
  • Received Date: 2014-02-19
  • The photodissociation dynamics of acetaldehyde in the radical channel CH3+HCO has been reinvestigated using time-sliced velocity map imaging technique in the photolysis wavelength range of 275?321 nm. The CH3 fragments have been probed via (2+1) resonance-enhanced multiphoton ionization. Images are measured for CH3 formed in the ground and excited states (v2=0 and 1) of the umbrella vibrational mode. For acetaldehyde dissociation on T1 state after intersystem crossing from S1 state, the products are formed with high translational energy release and low internal excitation. The rotational and vibrational energy of both fragments increases with increasing photodissociation energy. The triplet barrier height is estimated at 3.881±0.006 eV above the ground state of acetaldehyde.
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通讯作者: 陈斌, bchen63@163.com
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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Ion-Velocity Map Imaging Study of Photodissociation Dynamics of Acetaldehyde

doi: 10.1063/1674-0068/27/03/249-255

Abstract: The photodissociation dynamics of acetaldehyde in the radical channel CH3+HCO has been reinvestigated using time-sliced velocity map imaging technique in the photolysis wavelength range of 275?321 nm. The CH3 fragments have been probed via (2+1) resonance-enhanced multiphoton ionization. Images are measured for CH3 formed in the ground and excited states (v2=0 and 1) of the umbrella vibrational mode. For acetaldehyde dissociation on T1 state after intersystem crossing from S1 state, the products are formed with high translational energy release and low internal excitation. The rotational and vibrational energy of both fragments increases with increasing photodissociation energy. The triplet barrier height is estimated at 3.881±0.006 eV above the ground state of acetaldehyde.

Zhi-guo Zhang, Zhi-chao Chen, Cui-mei Zhang, Yan-ling Jin, Qun Zhang, Yang Chen, Cun-shun Huang, Xue-ming Yang. Ion-Velocity Map Imaging Study of Photodissociation Dynamics of Acetaldehyde[J]. Chinese Journal of Chemical Physics , 2014, 27(3): 249-255. doi: 10.1063/1674-0068/27/03/249-255
Citation: Zhi-guo Zhang, Zhi-chao Chen, Cui-mei Zhang, Yan-ling Jin, Qun Zhang, Yang Chen, Cun-shun Huang, Xue-ming Yang. Ion-Velocity Map Imaging Study of Photodissociation Dynamics of Acetaldehyde[J]. Chinese Journal of Chemical Physics , 2014, 27(3): 249-255. doi: 10.1063/1674-0068/27/03/249-255

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