Rong Zhang, Jun Li, Wen-juan Wu. Relative Chemical Shifts for Obtaining Accurate Chemical Shifts of Hydrogen Atoms in CH Groups[J]. Chinese Journal of Chemical Physics , 2014, 27(2): 240-242. doi: 10.1063/1674-0068/27/02/240-242
Citation: Rong Zhang, Jun Li, Wen-juan Wu. Relative Chemical Shifts for Obtaining Accurate Chemical Shifts of Hydrogen Atoms in CH Groups[J]. Chinese Journal of Chemical Physics , 2014, 27(2): 240-242. doi: 10.1063/1674-0068/27/02/240-242

Relative Chemical Shifts for Obtaining Accurate Chemical Shifts of Hydrogen Atoms in CH Groups

doi: 10.1063/1674-0068/27/02/240-242
Funds:  This work was supported by the National Natural Science Foundation of China (No.20903026), the Tal-ents Introduction Foundation for Universities of Guang-dong Province (No.2011), Scientific Research Foun-dation of the Natural Science Foundation of Guang-d
  • Received Date: 2013-09-04
  • Accurate chemical shifts of hydrogen atoms in CH groups are difficult to obtain. To solve this problem, relative chemical shifts are introduced. Internal and external standard methods were used to measure the chemical shifts in a whole-concentration of N-methylacetamide-water system. Determination of the chemical shifts of hydrogen atoms, especially those of CH groups, according to the two methods yielded significant differences. Relative chemical shifts were proven to be independent of the reference and may be applied to other systems.
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Relative Chemical Shifts for Obtaining Accurate Chemical Shifts of Hydrogen Atoms in CH Groups

doi: 10.1063/1674-0068/27/02/240-242
Funds:  This work was supported by the National Natural Science Foundation of China (No.20903026), the Tal-ents Introduction Foundation for Universities of Guang-dong Province (No.2011), Scientific Research Foun-dation of the Natural Science Foundation of Guang-d

Abstract: Accurate chemical shifts of hydrogen atoms in CH groups are difficult to obtain. To solve this problem, relative chemical shifts are introduced. Internal and external standard methods were used to measure the chemical shifts in a whole-concentration of N-methylacetamide-water system. Determination of the chemical shifts of hydrogen atoms, especially those of CH groups, according to the two methods yielded significant differences. Relative chemical shifts were proven to be independent of the reference and may be applied to other systems.

Rong Zhang, Jun Li, Wen-juan Wu. Relative Chemical Shifts for Obtaining Accurate Chemical Shifts of Hydrogen Atoms in CH Groups[J]. Chinese Journal of Chemical Physics , 2014, 27(2): 240-242. doi: 10.1063/1674-0068/27/02/240-242
Citation: Rong Zhang, Jun Li, Wen-juan Wu. Relative Chemical Shifts for Obtaining Accurate Chemical Shifts of Hydrogen Atoms in CH Groups[J]. Chinese Journal of Chemical Physics , 2014, 27(2): 240-242. doi: 10.1063/1674-0068/27/02/240-242

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