Dan-dan Kong, Yong-he Pan, Guo-dong Wang, Hai-bin Pan, Jun-fa Zhu. Growth and Electronic Properties of Ag Nanoparticles on Reduced CeO2-x(111) Films[J]. Chinese Journal of Chemical Physics , 2012, 25(6): 713-718. doi: 10.1088/1674-0068/25/06/713-718
Citation: Dan-dan Kong, Yong-he Pan, Guo-dong Wang, Hai-bin Pan, Jun-fa Zhu. Growth and Electronic Properties of Ag Nanoparticles on Reduced CeO2-x(111) Films[J]. Chinese Journal of Chemical Physics , 2012, 25(6): 713-718. doi: 10.1088/1674-0068/25/06/713-718

Growth and Electronic Properties of Ag Nanoparticles on Reduced CeO2-x(111) Films

doi: 10.1088/1674-0068/25/06/713-718
Funds:  This work was supported by the National Natural Science Foundation of China (No.20873128), the “Hun-dred Talents Program” of the Chinese Academy of Sci-ences, the Specialized Research Fund for the Doctoral Program of Higher Education (SRFDP) of Ministry ofEducation (No.200803580012), and the National Basic Research Program of China (2010CB923302).
  • Received Date: 2012-09-28
  • Ag nanoparticles grown on reduced CeO2-x thin films have been studied by X-ray photoelec-tron spectroscopy and resonant photoelectron spectroscopy of the valence band to understand the effect of oxygen vacancies in the CeO2-x thin films on the growth and interfacial elec-tronic properties of Ag. Ag grows as three-dimensional particles on the CeO2-x(111) surface at 300 K. Compared to the fully oxidized ceria substrate surface, Ag favors the growth of smaller particles with a larger particle density on the reduced ceria substrate surface, which can be attributed to the nucleation of Ag on oxygen vacancies. The binding energy of Ag3d increases when the Ag particle size decreases, which is mainly attributed to the final-state screening. The interfacial interaction between Ag and CeO2-x(111) is weak. The resonant enhancement of the 4f level of Ce3+ species in RPES indicates a partial Ce4+→Ce3+ re-duction after Ag deposited on reduced ceria surface. The sintering temperature of Ag on CeO1.85(111) surface during annealing is a little higher than that of Ag on CeO2(111) surface, indicating that Ag nanoparticles are more stable on the reduced ceria surface.
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Growth and Electronic Properties of Ag Nanoparticles on Reduced CeO2-x(111) Films

doi: 10.1088/1674-0068/25/06/713-718
Funds:  This work was supported by the National Natural Science Foundation of China (No.20873128), the “Hun-dred Talents Program” of the Chinese Academy of Sci-ences, the Specialized Research Fund for the Doctoral Program of Higher Education (SRFDP) of Ministry ofEducation (No.200803580012), and the National Basic Research Program of China (2010CB923302).

Abstract: Ag nanoparticles grown on reduced CeO2-x thin films have been studied by X-ray photoelec-tron spectroscopy and resonant photoelectron spectroscopy of the valence band to understand the effect of oxygen vacancies in the CeO2-x thin films on the growth and interfacial elec-tronic properties of Ag. Ag grows as three-dimensional particles on the CeO2-x(111) surface at 300 K. Compared to the fully oxidized ceria substrate surface, Ag favors the growth of smaller particles with a larger particle density on the reduced ceria substrate surface, which can be attributed to the nucleation of Ag on oxygen vacancies. The binding energy of Ag3d increases when the Ag particle size decreases, which is mainly attributed to the final-state screening. The interfacial interaction between Ag and CeO2-x(111) is weak. The resonant enhancement of the 4f level of Ce3+ species in RPES indicates a partial Ce4+→Ce3+ re-duction after Ag deposited on reduced ceria surface. The sintering temperature of Ag on CeO1.85(111) surface during annealing is a little higher than that of Ag on CeO2(111) surface, indicating that Ag nanoparticles are more stable on the reduced ceria surface.

Dan-dan Kong, Yong-he Pan, Guo-dong Wang, Hai-bin Pan, Jun-fa Zhu. Growth and Electronic Properties of Ag Nanoparticles on Reduced CeO2-x(111) Films[J]. Chinese Journal of Chemical Physics , 2012, 25(6): 713-718. doi: 10.1088/1674-0068/25/06/713-718
Citation: Dan-dan Kong, Yong-he Pan, Guo-dong Wang, Hai-bin Pan, Jun-fa Zhu. Growth and Electronic Properties of Ag Nanoparticles on Reduced CeO2-x(111) Films[J]. Chinese Journal of Chemical Physics , 2012, 25(6): 713-718. doi: 10.1088/1674-0068/25/06/713-718

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