Qian Yang, Dao-yong Chen. PEO-b-P4VP/Yttrium Hydroxide Hybrid Nanotubes as Supporter for Catalyst Gold Nanoparticles[J]. Chinese Journal of Chemical Physics , 2012, 25(3): 352-358. doi: 10.1088/1674-0068/25/03/352-358
Citation: Qian Yang, Dao-yong Chen. PEO-b-P4VP/Yttrium Hydroxide Hybrid Nanotubes as Supporter for Catalyst Gold Nanoparticles[J]. Chinese Journal of Chemical Physics , 2012, 25(3): 352-358. doi: 10.1088/1674-0068/25/03/352-358

PEO-b-P4VP/Yttrium Hydroxide Hybrid Nanotubes as Supporter for Catalyst Gold Nanoparticles

doi: 10.1088/1674-0068/25/03/352-358
Funds:  This work was supported by the National Natu-ral Science Foundation of China (No.50825303 and No.30890140), the Ministry of Science and Technology of China (No.2009CB-930400 and No.2011CB932503), and the Shanghai Committee of Science and Technol-ogy, Chin
  • Received Date: 2012-04-19
  • The adsorption of poly (ethylene oxide)-b-poly(4-vinylpyridine)(PEO-b-P4VP) micelles onto the surface of yttrium hydroxide nanotubes (YNTs) resulted in the hybrid nanotubes with a dense P4VP inner layer and a stretched PEO outer layer surrounding YNTs. The dense P4VP layer was further stabilized by the crosslinking using 1,4-dibromobutane as the crosslinker. Then, the crosslinked hybrid nanotubes (CHNTs) were used as a novel nano supporter for loading the catalyst gold nanoparticles (GNPs) within the crosslinked P4VP layer. The resultant GNPs/CHNTs (GNTs loaded on CHNTs) were applied to catalyze the reduction reaction of p-nitrophenol. The results indicate that this novel nano supporter has advantages such as good dispersity in the suspension, high capacity in loading GNPs (0.87 mmol/g), high catalytic activity of the loaded GNPs (12.9 μmol-1min-1), and good reusability of GNTs/CHNTs.
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PEO-b-P4VP/Yttrium Hydroxide Hybrid Nanotubes as Supporter for Catalyst Gold Nanoparticles

doi: 10.1088/1674-0068/25/03/352-358
Funds:  This work was supported by the National Natu-ral Science Foundation of China (No.50825303 and No.30890140), the Ministry of Science and Technology of China (No.2009CB-930400 and No.2011CB932503), and the Shanghai Committee of Science and Technol-ogy, Chin

Abstract: The adsorption of poly (ethylene oxide)-b-poly(4-vinylpyridine)(PEO-b-P4VP) micelles onto the surface of yttrium hydroxide nanotubes (YNTs) resulted in the hybrid nanotubes with a dense P4VP inner layer and a stretched PEO outer layer surrounding YNTs. The dense P4VP layer was further stabilized by the crosslinking using 1,4-dibromobutane as the crosslinker. Then, the crosslinked hybrid nanotubes (CHNTs) were used as a novel nano supporter for loading the catalyst gold nanoparticles (GNPs) within the crosslinked P4VP layer. The resultant GNPs/CHNTs (GNTs loaded on CHNTs) were applied to catalyze the reduction reaction of p-nitrophenol. The results indicate that this novel nano supporter has advantages such as good dispersity in the suspension, high capacity in loading GNPs (0.87 mmol/g), high catalytic activity of the loaded GNPs (12.9 μmol-1min-1), and good reusability of GNTs/CHNTs.

Qian Yang, Dao-yong Chen. PEO-b-P4VP/Yttrium Hydroxide Hybrid Nanotubes as Supporter for Catalyst Gold Nanoparticles[J]. Chinese Journal of Chemical Physics , 2012, 25(3): 352-358. doi: 10.1088/1674-0068/25/03/352-358
Citation: Qian Yang, Dao-yong Chen. PEO-b-P4VP/Yttrium Hydroxide Hybrid Nanotubes as Supporter for Catalyst Gold Nanoparticles[J]. Chinese Journal of Chemical Physics , 2012, 25(3): 352-358. doi: 10.1088/1674-0068/25/03/352-358

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