Jun-he Du, An-wen Liu, V. I. Perevalov, S. A. Tashkun, Shui-ming Hu. High-resolution Infrared Spectroscopy of 15N216O in 1650-3450 cm-1[J]. Chinese Journal of Chemical Physics , 2011, 24(5): 611-619. doi: 10.1088/1674-0068/24/05/611-619
Citation: Jun-he Du, An-wen Liu, V. I. Perevalov, S. A. Tashkun, Shui-ming Hu. High-resolution Infrared Spectroscopy of 15N216O in 1650-3450 cm-1[J]. Chinese Journal of Chemical Physics , 2011, 24(5): 611-619. doi: 10.1088/1674-0068/24/05/611-619

High-resolution Infrared Spectroscopy of 15N216O in 1650-3450 cm-1

doi: 10.1088/1674-0068/24/05/611-619
Funds:  This work is supported by the National Natu-ral Science Foundation of China (No.20903085), the NKBRSF 2010CB9230, and RFBR-Russia (No.06-05-39016). The support of the Groupement de Recherche International SAMIA (Spectroscopie d'Absorption des Molécules d'Intér^et Atmosphêrique) between CNRS (France), RFBR (Russia) and CAS (China) is also ac-knowledged.
  • Received Date: 2011-10-01
  • High-resolution ro-vibrational spectroscopy of 15N216O in 1650-3450 cm-1 region is studied using highly enriched isotopologue sample. The positions of more than 7300 lines of 15N216O isotopologue were measured with a typical accuracy of 5.0×10-4 cm-1. The transitions were rovibrationally assigned on the basis of the global effective Hamiltonian model. The band by band analysis allowed for the determination of the rovibrational parameters of a total of 73 bands. 29 of them are newly reported and more rotational transitions have been observed for the others. The maximum deviation of the preidictions of the effective Hamiltonian model is up to 0.70 cm-1 for the 15N216O species.
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High-resolution Infrared Spectroscopy of 15N216O in 1650-3450 cm-1

doi: 10.1088/1674-0068/24/05/611-619
Funds:  This work is supported by the National Natu-ral Science Foundation of China (No.20903085), the NKBRSF 2010CB9230, and RFBR-Russia (No.06-05-39016). The support of the Groupement de Recherche International SAMIA (Spectroscopie d'Absorption des Molécules d'Intér^et Atmosphêrique) between CNRS (France), RFBR (Russia) and CAS (China) is also ac-knowledged.

Abstract: High-resolution ro-vibrational spectroscopy of 15N216O in 1650-3450 cm-1 region is studied using highly enriched isotopologue sample. The positions of more than 7300 lines of 15N216O isotopologue were measured with a typical accuracy of 5.0×10-4 cm-1. The transitions were rovibrationally assigned on the basis of the global effective Hamiltonian model. The band by band analysis allowed for the determination of the rovibrational parameters of a total of 73 bands. 29 of them are newly reported and more rotational transitions have been observed for the others. The maximum deviation of the preidictions of the effective Hamiltonian model is up to 0.70 cm-1 for the 15N216O species.

Jun-he Du, An-wen Liu, V. I. Perevalov, S. A. Tashkun, Shui-ming Hu. High-resolution Infrared Spectroscopy of 15N216O in 1650-3450 cm-1[J]. Chinese Journal of Chemical Physics , 2011, 24(5): 611-619. doi: 10.1088/1674-0068/24/05/611-619
Citation: Jun-he Du, An-wen Liu, V. I. Perevalov, S. A. Tashkun, Shui-ming Hu. High-resolution Infrared Spectroscopy of 15N216O in 1650-3450 cm-1[J]. Chinese Journal of Chemical Physics , 2011, 24(5): 611-619. doi: 10.1088/1674-0068/24/05/611-619

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