Tao Sun, You-yuan Zhao, Ming Lu. Hydrogenation and Ammoniation of SrTiO3 for an Enhanced Visible-light Photocatalysis[J]. Chinese Journal of Chemical Physics , 2012, 25(1): 86-90. doi: 10.1088/1674-0068/25/01/86-90
Citation: Tao Sun, You-yuan Zhao, Ming Lu. Hydrogenation and Ammoniation of SrTiO3 for an Enhanced Visible-light Photocatalysis[J]. Chinese Journal of Chemical Physics , 2012, 25(1): 86-90. doi: 10.1088/1674-0068/25/01/86-90

Hydrogenation and Ammoniation of SrTiO3 for an Enhanced Visible-light Photocatalysis

doi: 10.1088/1674-0068/25/01/86-90
Funds:  This work was supported by the National Natu-ral Science Foundation of China (No.10974034 and No.60638010). We thank Pei-nan Wang and Lan Mi for their assistance in experiments.
  • Received Date: 2011-06-16
  • Hydrogenation and ammoniation of SrTiO3 (STO), a normal ultraviolet photocatalyst, were performed by annealing STO〈100〉in H2:N2=5%:95% and NH3, respectively, at various tem-peratures T. It was found that hydrogenation at T≥900 oC remarkably enhanced the UV photocatalytic ability of STO, but the visible-light photocatalysis was still unavailable, while ammoniation at T≥800 oC introduced the N doping, resulting in visible-light photocat-alytic activity. Furthermore, when a hydrogenated STO was subjected to ammoniation, the visible-light photocatalytic ability was nearly the same as that of the ammoniated one; but the hydrogenation of an ammoniated one significantly enhanced visible-light photocatalysis, indicating a synergetic effect of hydrogenation and ammoniation. Discussions and identifi-cations have been made to analyze these results.
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Hydrogenation and Ammoniation of SrTiO3 for an Enhanced Visible-light Photocatalysis

doi: 10.1088/1674-0068/25/01/86-90
Funds:  This work was supported by the National Natu-ral Science Foundation of China (No.10974034 and No.60638010). We thank Pei-nan Wang and Lan Mi for their assistance in experiments.

Abstract: Hydrogenation and ammoniation of SrTiO3 (STO), a normal ultraviolet photocatalyst, were performed by annealing STO〈100〉in H2:N2=5%:95% and NH3, respectively, at various tem-peratures T. It was found that hydrogenation at T≥900 oC remarkably enhanced the UV photocatalytic ability of STO, but the visible-light photocatalysis was still unavailable, while ammoniation at T≥800 oC introduced the N doping, resulting in visible-light photocat-alytic activity. Furthermore, when a hydrogenated STO was subjected to ammoniation, the visible-light photocatalytic ability was nearly the same as that of the ammoniated one; but the hydrogenation of an ammoniated one significantly enhanced visible-light photocatalysis, indicating a synergetic effect of hydrogenation and ammoniation. Discussions and identifi-cations have been made to analyze these results.

Tao Sun, You-yuan Zhao, Ming Lu. Hydrogenation and Ammoniation of SrTiO3 for an Enhanced Visible-light Photocatalysis[J]. Chinese Journal of Chemical Physics , 2012, 25(1): 86-90. doi: 10.1088/1674-0068/25/01/86-90
Citation: Tao Sun, You-yuan Zhao, Ming Lu. Hydrogenation and Ammoniation of SrTiO3 for an Enhanced Visible-light Photocatalysis[J]. Chinese Journal of Chemical Physics , 2012, 25(1): 86-90. doi: 10.1088/1674-0068/25/01/86-90

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