H. F. Pang, A. S. C. Cheung . Laser Induced Fluorescence Spectroscopy of IrN[J]. Chinese Journal of Chemical Physics , 2009, 22(2): 157-161. doi: 10.1088/1674-0068/22/02/157-161
Citation: H. F. Pang, A. S. C. Cheung . Laser Induced Fluorescence Spectroscopy of IrN[J]. Chinese Journal of Chemical Physics , 2009, 22(2): 157-161. doi: 10.1088/1674-0068/22/02/157-161

Laser Induced Fluorescence Spectroscopy of IrN

doi: 10.1088/1674-0068/22/02/157-161
Funds:  The work was supported by the Research Grants Council of the Hong Kong Special Administrative Re-gion, China (No.HKU7015/04P). We would also like to thank Dr. Joanne W. H. Leung and Dr. Jianjun Ye for providing technical help.
  • Received Date: 2009-02-14
  • High resolution laser induced fluorescence spectra of IrN in the spectral region between 394 and 520 nm were recorded using laser vaporization/reaction free jet expansion and laser induced fluorescence spectroscopy. Seven new vibronic transition bands were observed and analyzed. Two Ω=1 and five Ω=0 new states were identified. Least squares fit of rotationally resolved transition lines yielded accurate molecular constants for the upper states. Spectra of isotopic molecules were observed, which provided confirmation for the vibrational assignment. Comparison of the observed electronic states of IrB, IrC, and IrN provides a good understanding of the chemical bonding of this group of molecules.
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Laser Induced Fluorescence Spectroscopy of IrN

doi: 10.1088/1674-0068/22/02/157-161
Funds:  The work was supported by the Research Grants Council of the Hong Kong Special Administrative Re-gion, China (No.HKU7015/04P). We would also like to thank Dr. Joanne W. H. Leung and Dr. Jianjun Ye for providing technical help.

Abstract: High resolution laser induced fluorescence spectra of IrN in the spectral region between 394 and 520 nm were recorded using laser vaporization/reaction free jet expansion and laser induced fluorescence spectroscopy. Seven new vibronic transition bands were observed and analyzed. Two Ω=1 and five Ω=0 new states were identified. Least squares fit of rotationally resolved transition lines yielded accurate molecular constants for the upper states. Spectra of isotopic molecules were observed, which provided confirmation for the vibrational assignment. Comparison of the observed electronic states of IrB, IrC, and IrN provides a good understanding of the chemical bonding of this group of molecules.

H. F. Pang, A. S. C. Cheung . Laser Induced Fluorescence Spectroscopy of IrN[J]. Chinese Journal of Chemical Physics , 2009, 22(2): 157-161. doi: 10.1088/1674-0068/22/02/157-161
Citation: H. F. Pang, A. S. C. Cheung . Laser Induced Fluorescence Spectroscopy of IrN[J]. Chinese Journal of Chemical Physics , 2009, 22(2): 157-161. doi: 10.1088/1674-0068/22/02/157-161

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