Electron Momentum Spectroscopy of Ethanethiol Complete Valence Shell
- Received Date: 2008-05-20
- Ethanethiol, Electron momentum spectroscopy, Valence orbital, Satellite line, Binding energyspectrum
Abstract: The binding energy spectra and electron momentum distributions for the complete valence orbitals of ethanethiol were measured for the first time by binary (e, 2e) electron momentum spectroscopy employing non-coplanar symmetric kinematics at an impact energy of 1200 eV plus binding energy. The experimental results are generally consistent with the theoretical calculations using density functional theory and Hartree-Fock methods with various basis sets. A possible satellite line at 17.8 eV in binding energy spectrum was observed and studied by electron momentum spectroscopy.
|Citation:||Xin-xia Xue, Mi Yan, Fang Wu, Xu Shan, Ke-zun Xu, Xiang-jun Chen. Electron Momentum Spectroscopy of Ethanethiol Complete Valence Shell[J]. Chinese Journal of Chemical Physics , 2008, 21(6): 515-520. doi: 10.1088/1674-0068/21/06/515-520|