Yan-qing Ni a, Jian Li b, Feng-cai Ma a. Collision-induced Rotational Energy Transfer in an Atom-Diatom System[J]. Chinese Journal of Chemical Physics , 2008, 21(5): 457-462. doi: 10.1088/1674-0068/21/05/457-462
Citation: Yan-qing Ni a, Jian Li b, Feng-cai Ma a. Collision-induced Rotational Energy Transfer in an Atom-Diatom System[J]. Chinese Journal of Chemical Physics , 2008, 21(5): 457-462. doi: 10.1088/1674-0068/21/05/457-462

Collision-induced Rotational Energy Transfer in an Atom-Diatom System

doi: 10.1088/1674-0068/21/05/457-462
Funds:  This work was supported by the National Natural Science Foundation of China (No.10374040) and the Educational Department of Liaoning Province (No.20060347).
  • Received Date: 2008-03-13
  • As a further theoretical study of the collision-induced quantum interference on rotational energy transfer in an atom-diatom system, based on the first-Born approximation of time-dependent perturbation theory, taking into account the anisotropic Lennard-Jones interaction potential and the long-range interaction potential, the differential interference angles in singlet-triplet mixed states of CO A1Ⅱ(v=0)~e3∑-(v=1)system in collision with He, Ne, Ar, and other partners were calculated theoretically. The relationships of differential interference angle versus impact parameters, including collision parameter b and velocity, are obtained.
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Collision-induced Rotational Energy Transfer in an Atom-Diatom System

doi: 10.1088/1674-0068/21/05/457-462
Funds:  This work was supported by the National Natural Science Foundation of China (No.10374040) and the Educational Department of Liaoning Province (No.20060347).

Abstract: As a further theoretical study of the collision-induced quantum interference on rotational energy transfer in an atom-diatom system, based on the first-Born approximation of time-dependent perturbation theory, taking into account the anisotropic Lennard-Jones interaction potential and the long-range interaction potential, the differential interference angles in singlet-triplet mixed states of CO A1Ⅱ(v=0)~e3∑-(v=1)system in collision with He, Ne, Ar, and other partners were calculated theoretically. The relationships of differential interference angle versus impact parameters, including collision parameter b and velocity, are obtained.

Yan-qing Ni a, Jian Li b, Feng-cai Ma a. Collision-induced Rotational Energy Transfer in an Atom-Diatom System[J]. Chinese Journal of Chemical Physics , 2008, 21(5): 457-462. doi: 10.1088/1674-0068/21/05/457-462
Citation: Yan-qing Ni a, Jian Li b, Feng-cai Ma a. Collision-induced Rotational Energy Transfer in an Atom-Diatom System[J]. Chinese Journal of Chemical Physics , 2008, 21(5): 457-462. doi: 10.1088/1674-0068/21/05/457-462

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