Santosh S. Jadhav, Sagar E. Shirsath, B. G. Toksha, S. J. Shukla, K. M. Jadhav. Effect of Cation Proportion on the Structural and Magnetic Properties of Ni-Zn Ferrites Nano-Size Particles Prepared By Co-Precipitation Technique[J]. Chinese Journal of Chemical Physics , 2008, 21(4): 381-386. doi: 10.1088/1674-0068/21/04/381-386
Citation: Santosh S. Jadhav, Sagar E. Shirsath, B. G. Toksha, S. J. Shukla, K. M. Jadhav. Effect of Cation Proportion on the Structural and Magnetic Properties of Ni-Zn Ferrites Nano-Size Particles Prepared By Co-Precipitation Technique[J]. Chinese Journal of Chemical Physics , 2008, 21(4): 381-386. doi: 10.1088/1674-0068/21/04/381-386

Effect of Cation Proportion on the Structural and Magnetic Properties of Ni-Zn Ferrites Nano-Size Particles Prepared By Co-Precipitation Technique

doi: 10.1088/1674-0068/21/04/381-386
  • Received Date: 2008-02-07
  • Rev Recd Date: 2008-05-28
  • Ferrites having general formula Ni1-xZnxFe2O4 with x=0.0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, and 0.7 were prepared by wet chemical co-precipitation method. The structural and magnetic properties were studied by means of X-ray diffraction, magnetization, and AC susceptibility measurements. The X-ray analysis confirmed the single-phase formation of the samples. The lattice parameter obtained from XRD data was found to increase with Zn content x. The cation distribution was studied by X-ray intensity ratio calculations. Magnetization results exhibit collinear ferrimagnetic structure for x<0.4, and which changes to non-collinear for x>0.4. Curie temperature TC obtained from AC susceptibility data decreases with increasing x.
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Effect of Cation Proportion on the Structural and Magnetic Properties of Ni-Zn Ferrites Nano-Size Particles Prepared By Co-Precipitation Technique

doi: 10.1088/1674-0068/21/04/381-386

Abstract: Ferrites having general formula Ni1-xZnxFe2O4 with x=0.0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, and 0.7 were prepared by wet chemical co-precipitation method. The structural and magnetic properties were studied by means of X-ray diffraction, magnetization, and AC susceptibility measurements. The X-ray analysis confirmed the single-phase formation of the samples. The lattice parameter obtained from XRD data was found to increase with Zn content x. The cation distribution was studied by X-ray intensity ratio calculations. Magnetization results exhibit collinear ferrimagnetic structure for x<0.4, and which changes to non-collinear for x>0.4. Curie temperature TC obtained from AC susceptibility data decreases with increasing x.

Santosh S. Jadhav, Sagar E. Shirsath, B. G. Toksha, S. J. Shukla, K. M. Jadhav. Effect of Cation Proportion on the Structural and Magnetic Properties of Ni-Zn Ferrites Nano-Size Particles Prepared By Co-Precipitation Technique[J]. Chinese Journal of Chemical Physics , 2008, 21(4): 381-386. doi: 10.1088/1674-0068/21/04/381-386
Citation: Santosh S. Jadhav, Sagar E. Shirsath, B. G. Toksha, S. J. Shukla, K. M. Jadhav. Effect of Cation Proportion on the Structural and Magnetic Properties of Ni-Zn Ferrites Nano-Size Particles Prepared By Co-Precipitation Technique[J]. Chinese Journal of Chemical Physics , 2008, 21(4): 381-386. doi: 10.1088/1674-0068/21/04/381-386

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