Xian-feng Zheng, Ting-ting Wang, Chun-yan Li, Yang Chen, Jing-song Zhang. Observation of a New 2§ Excited Electronic State of SF by Resonance-Enhanced Multiphoton Ionization Spectroscopy[J]. Chinese Journal of Chemical Physics , 2007, 20(4): 372-376. doi: 10.1088/1674-0068/20/04/372-376
Citation: Xian-feng Zheng, Ting-ting Wang, Chun-yan Li, Yang Chen, Jing-song Zhang. Observation of a New 2§ Excited Electronic State of SF by Resonance-Enhanced Multiphoton Ionization Spectroscopy[J]. Chinese Journal of Chemical Physics , 2007, 20(4): 372-376. doi: 10.1088/1674-0068/20/04/372-376

Observation of a New 2§ Excited Electronic State of SF by Resonance-Enhanced Multiphoton Ionization Spectroscopy

doi: 10.1088/1674-0068/20/04/372-376
Funds:  This work was partially supported by the NationalNatural Science Foundation of China (No.20328305,No.20433080), and Chinese Academy of Science(KJCX2-SW-H08).
  • Received Date: 2007-07-25
  • Rev Recd Date: 2007-08-09
  • The (2+1) resonance-enhanced multiphoton ionization (REMPI) spectrum of SF has been obtained in the single-photon wavelength region of 307-321 nm. Five vibronic bands were observed and assigned to the two-photon transitions from the ground state to a 2§ Rydberg state. The term value Te, vibrational frequency, and the rotational constant of the 2§ Rydberg state were determined. Another 2P state was observed near 312 nm.
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Observation of a New 2§ Excited Electronic State of SF by Resonance-Enhanced Multiphoton Ionization Spectroscopy

doi: 10.1088/1674-0068/20/04/372-376
Funds:  This work was partially supported by the NationalNatural Science Foundation of China (No.20328305,No.20433080), and Chinese Academy of Science(KJCX2-SW-H08).

Abstract: The (2+1) resonance-enhanced multiphoton ionization (REMPI) spectrum of SF has been obtained in the single-photon wavelength region of 307-321 nm. Five vibronic bands were observed and assigned to the two-photon transitions from the ground state to a 2§ Rydberg state. The term value Te, vibrational frequency, and the rotational constant of the 2§ Rydberg state were determined. Another 2P state was observed near 312 nm.

Xian-feng Zheng, Ting-ting Wang, Chun-yan Li, Yang Chen, Jing-song Zhang. Observation of a New 2§ Excited Electronic State of SF by Resonance-Enhanced Multiphoton Ionization Spectroscopy[J]. Chinese Journal of Chemical Physics , 2007, 20(4): 372-376. doi: 10.1088/1674-0068/20/04/372-376
Citation: Xian-feng Zheng, Ting-ting Wang, Chun-yan Li, Yang Chen, Jing-song Zhang. Observation of a New 2§ Excited Electronic State of SF by Resonance-Enhanced Multiphoton Ionization Spectroscopy[J]. Chinese Journal of Chemical Physics , 2007, 20(4): 372-376. doi: 10.1088/1674-0068/20/04/372-376

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