?Jun-song Yang, Qian-wang Chen. Synthesis and Characterization of Cobalt-Carbon Core-Shell Microspheres in Supercritical Carbon Dioxide System[J]. Chinese Journal of Chemical Physics , 2008, 21(1): 76-80. doi: 10.1088/1674-0068/21/01/76-80
Citation: ?Jun-song Yang, Qian-wang Chen. Synthesis and Characterization of Cobalt-Carbon Core-Shell Microspheres in Supercritical Carbon Dioxide System[J]. Chinese Journal of Chemical Physics , 2008, 21(1): 76-80. doi: 10.1088/1674-0068/21/01/76-80

Synthesis and Characterization of Cobalt-Carbon Core-Shell Microspheres in Supercritical Carbon Dioxide System

doi: 10.1088/1674-0068/21/01/76-80
Funds:  This work was supported by the National Natural Science Foundation of China (No.20273066).
  • Received Date: 2007-03-15
  • Rev Recd Date: 2007-04-23
  • The synthesis of cobalt-carbon core-shell microspheres in supercritical carbon dioxide system was investigated. Cobalt-carbon core-shell microspheres with diameter of about 1 μm were prepared at 350 oC for 12 h in a closed vessel containing an appropriate amount of bis(cyclopentadienyl)cobalt powder and dry ice. Characterization by a variety of techniques, including X-ray powder diffraction, X-ray photoelectron spectroscopy, Transmission electron microscope, Fourier transform infrared spectrum and Raman spectroscopy analysis reveals that each cobalt-carbon core-shell microsphere is made up of an amorphous cobalt core with diameter less than 1 μm and an amorphous carbon shell with thickness of about 200 nm. The possible growth mechanism of cobalt-carbon core-shell microspheres is discussed, based on the pyrolysis of bis(cyclopentadienyl)cobalt in supercritical carbon dioxide and the deposition of carbon or carbon clusters with odd electrons on the surface of magnetic cobalt cores due to magnetic attraction. Magnetic measurements show 141.41 emu/g of saturation magnetization of a typical sample, which is lower than the 168 emu/g of the corresponding metal cobalt bulk material. This is attributed to the considerable mass of the carbon shell and amorphous nature of the magnetic core. Control of magnetism in the cobalt-carbon core-shell microspheres was achieved by annealing treatments.
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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Synthesis and Characterization of Cobalt-Carbon Core-Shell Microspheres in Supercritical Carbon Dioxide System

doi: 10.1088/1674-0068/21/01/76-80
Funds:  This work was supported by the National Natural Science Foundation of China (No.20273066).

Abstract: The synthesis of cobalt-carbon core-shell microspheres in supercritical carbon dioxide system was investigated. Cobalt-carbon core-shell microspheres with diameter of about 1 μm were prepared at 350 oC for 12 h in a closed vessel containing an appropriate amount of bis(cyclopentadienyl)cobalt powder and dry ice. Characterization by a variety of techniques, including X-ray powder diffraction, X-ray photoelectron spectroscopy, Transmission electron microscope, Fourier transform infrared spectrum and Raman spectroscopy analysis reveals that each cobalt-carbon core-shell microsphere is made up of an amorphous cobalt core with diameter less than 1 μm and an amorphous carbon shell with thickness of about 200 nm. The possible growth mechanism of cobalt-carbon core-shell microspheres is discussed, based on the pyrolysis of bis(cyclopentadienyl)cobalt in supercritical carbon dioxide and the deposition of carbon or carbon clusters with odd electrons on the surface of magnetic cobalt cores due to magnetic attraction. Magnetic measurements show 141.41 emu/g of saturation magnetization of a typical sample, which is lower than the 168 emu/g of the corresponding metal cobalt bulk material. This is attributed to the considerable mass of the carbon shell and amorphous nature of the magnetic core. Control of magnetism in the cobalt-carbon core-shell microspheres was achieved by annealing treatments.

?Jun-song Yang, Qian-wang Chen. Synthesis and Characterization of Cobalt-Carbon Core-Shell Microspheres in Supercritical Carbon Dioxide System[J]. Chinese Journal of Chemical Physics , 2008, 21(1): 76-80. doi: 10.1088/1674-0068/21/01/76-80
Citation: ?Jun-song Yang, Qian-wang Chen. Synthesis and Characterization of Cobalt-Carbon Core-Shell Microspheres in Supercritical Carbon Dioxide System[J]. Chinese Journal of Chemical Physics , 2008, 21(1): 76-80. doi: 10.1088/1674-0068/21/01/76-80

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