Jing Xu, Quan-de Wang, Quan Zhu, Ke-xiang Fu, Fu-cheng He, Xiang-yuan Li. Time-Dependent Stokes Shift from Solvent Dielectric Relaxation[J]. Chinese Journal of Chemical Physics , 2010, 23(3): 297-302. doi: 10.1088/1674-0068/23/03/297-302
Citation: Jing Xu, Quan-de Wang, Quan Zhu, Ke-xiang Fu, Fu-cheng He, Xiang-yuan Li. Time-Dependent Stokes Shift from Solvent Dielectric Relaxation[J]. Chinese Journal of Chemical Physics , 2010, 23(3): 297-302. doi: 10.1088/1674-0068/23/03/297-302

Time-Dependent Stokes Shift from Solvent Dielectric Relaxation

doi: 10.1088/1674-0068/23/03/297-302
Funds:  This work was supported by the National Natu-ral Science Foundation of China (No.20625311 andNo.20903067). The authors would like to thank Asso-ciate Professor Francesca Ingrosso for help and critical reading of the manuscript.
  • Received Date: 2009-12-20
  • The Stokes shift response function, which is related to the time dependent solvation energy, is calculated with the dielectric response function and a novel expression of nonequilibrium solvation energy. In the derivation, relationship between the polarization and the dielec-tric response function is used. With the dipole-in-a-sphere model applied to the system coumarin 343 and water as the solvent, encouraging agreement with the experimental data from Jimenez et al. is obtained [Nature 369, 471 (1994)].
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Time-Dependent Stokes Shift from Solvent Dielectric Relaxation

doi: 10.1088/1674-0068/23/03/297-302
Funds:  This work was supported by the National Natu-ral Science Foundation of China (No.20625311 andNo.20903067). The authors would like to thank Asso-ciate Professor Francesca Ingrosso for help and critical reading of the manuscript.

Abstract: The Stokes shift response function, which is related to the time dependent solvation energy, is calculated with the dielectric response function and a novel expression of nonequilibrium solvation energy. In the derivation, relationship between the polarization and the dielec-tric response function is used. With the dipole-in-a-sphere model applied to the system coumarin 343 and water as the solvent, encouraging agreement with the experimental data from Jimenez et al. is obtained [Nature 369, 471 (1994)].

Jing Xu, Quan-de Wang, Quan Zhu, Ke-xiang Fu, Fu-cheng He, Xiang-yuan Li. Time-Dependent Stokes Shift from Solvent Dielectric Relaxation[J]. Chinese Journal of Chemical Physics , 2010, 23(3): 297-302. doi: 10.1088/1674-0068/23/03/297-302
Citation: Jing Xu, Quan-de Wang, Quan Zhu, Ke-xiang Fu, Fu-cheng He, Xiang-yuan Li. Time-Dependent Stokes Shift from Solvent Dielectric Relaxation[J]. Chinese Journal of Chemical Physics , 2010, 23(3): 297-302. doi: 10.1088/1674-0068/23/03/297-302

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