Time-Dependent Stokes Shift from Solvent Dielectric Relaxation
- Received Date: 2009-12-20
Abstract: The Stokes shift response function, which is related to the time dependent solvation energy, is calculated with the dielectric response function and a novel expression of nonequilibrium solvation energy. In the derivation, relationship between the polarization and the dielec-tric response function is used. With the dipole-in-a-sphere model applied to the system coumarin 343 and water as the solvent, encouraging agreement with the experimental data from Jimenez et al. is obtained [Nature 369, 471 (1994)].
|Citation:||Jing Xu, Quan-de Wang, Quan Zhu, Ke-xiang Fu, Fu-cheng He, Xiang-yuan Li. Time-Dependent Stokes Shift from Solvent Dielectric Relaxation[J]. Chinese Journal of Chemical Physics , 2010, 23(3): 297-302. doi: 10.1088/1674-0068/23/03/297-302|