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Wang Jun, Zhao Lifen, Yang Dongmei, Wang Zhichang. Isopiestic Studies on H2O+KCl(sat)+NaCl+NH4Cl[J]. Chinese Journal of Chemical Physics , 2005, 18(3): 453-456. DOI: 10.1088/1674-0068/18/3/453-456
Citation: Wang Jun, Zhao Lifen, Yang Dongmei, Wang Zhichang. Isopiestic Studies on H2O+KCl(sat)+NaCl+NH4Cl[J]. Chinese Journal of Chemical Physics , 2005, 18(3): 453-456. DOI: 10.1088/1674-0068/18/3/453-456
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Isopiestic Studies on H2O+KCl(sat)+NaCl+NH4Cl

  • Department of Chemistry, Northeastern University, Shenyang 110004

Funds: Project supported by the Special Research Found of Doctor's Program(20020145010).
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  • Received Date: March 30, 2004
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  • Isopiestic measurements have been carried out at 298.15 K for the quaternary aqueous solution H2O+KCl(sat)+NaCl+NH4Cl saturated with potassium chloride and its ternary subsystems H2O+KCl (sat)+NaCl and H2O+KCl(sat)+NH4Cl. Taking sodium chloride (aq) or calcium chloride (aq) as reference solutions, osm otic coefficients and water activities of the aqueous solution were determined. The experiment results show that the isopiestic actions of the quaternary system related to its ternary sub-systems are in excellent agreement with the ideallike solution model.
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