Vacuum Ultraviolet Free-Electron Laser Photoionization Mass Spectrometry of Alpha-pinene Ozonolysis

Xiangyu Zang; Zhaoyan Zhang; Chong Wang; Tiantong Wang; Huijun Zheng; Hua Xie; Jiayue Yang; Dongxu Dai; Guorong Wu; Weiqing Zhang; Gang Li; Xueming Yang; Ling Jiang

doi:10.1063/1674-0068/cjcp2111220

Volume 35 Issue 2

Apr. 2022

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Article Navigation > Chinese Journal of Chemical Physics > 2022 > 35(2): 281-288

Xiangyu Zang, Zhaoyan Zhang, Chong Wang, Tiantong Wang, Huijun Zheng, Hua Xie, Jiayue Yang, Dongxu Dai, Guorong Wu, Weiqing Zhang, Gang Li, Xueming Yang, Ling Jiang. Vacuum Ultraviolet Free-Electron Laser Photoionization Mass Spectrometry of Alpha-pinene Ozonolysis[J]. Chinese Journal of Chemical Physics , 2022, 35(2): 281-288. doi: 10.1063/1674-0068/cjcp2111220

Citation:

Xiangyu Zang, Zhaoyan Zhang, Chong Wang, Tiantong Wang, Huijun Zheng, Hua Xie, Jiayue Yang, Dongxu Dai, Guorong Wu, Weiqing Zhang, Gang Li, Xueming Yang, Ling Jiang. Vacuum Ultraviolet Free-Electron Laser Photoionization Mass Spectrometry of Alpha-pinene Ozonolysis[J]. Chinese Journal of Chemical Physics , 2022, 35(2): 281-288. doi: 10.1063/1674-0068/cjcp2111220

Citation:

Xiangyu Zang, Zhaoyan Zhang, Chong Wang, Tiantong Wang, Huijun Zheng, Hua Xie, Jiayue Yang, Dongxu Dai, Guorong Wu, Weiqing Zhang, Gang Li, Xueming Yang, Ling Jiang. Vacuum Ultraviolet Free-Electron Laser Photoionization Mass Spectrometry of Alpha-pinene Ozonolysis[J]. Chinese Journal of Chemical Physics , 2022, 35(2): 281-288. doi: 10.1063/1674-0068/cjcp2111220

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Vacuum Ultraviolet Free-Electron Laser Photoionization Mass Spectrometry of Alpha-pinene Ozonolysis

doi: 10.1063/1674-0068/cjcp2111220

Xiangyu Zang^{a, b, c, ‡},
Zhaoyan Zhang^{b, c, ‡},
Chong Wang^{b, c},
Tiantong Wang^{b, c},
Huijun Zheng^{b, c},
Hua Xie^b,
Jiayue Yang^b,
Dongxu Dai^b,
Guorong Wu^b,
Weiqing Zhang^b,
Gang Li^{b
,
,},
Xueming Yang^{a, b, c, d},
Ling Jiang^{b
,
,}

a.
Zhang Dayu School of Chemistry, Dalian University of Technology, Dalian 116024, China
b.
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China
d.
Department of Chemistry, School of Science, Southern University of Science and Technology, Shenzhen 518055, China

More Information

Corresponding author: Gang Li, E-mail: gli@dicp.ac.cn; Ling Jiang, E-mail: ljiang@dicp.ac.cn
Received Date: 2021-11-02
Accepted Date: 2022-01-04
Publish Date: 2022-04-27

Abstract

Abstract

$\alpha$-pinene is the most abundant monoterpene that represents an important family of volatile organic compounds. Molecular identification of key transient compounds during the $\alpha$-pinene ozonolysis has been proven to be a challenging experimental target because of a large number of intermediates and products involved. Here we exploit the recently developed hybrid instruments that integrate aerosol mass spectrometry with a vacuum ultraviolet free-electron laser to study the $\alpha$-pinene ozonolysis. The experiments of $\alpha$-pinene ozonolysis are performed in an indoor smog chamber, with reactor having a volume of 2 m$^3$ which is made of fluorinated ethylene propylene film. Distinct mass spectral peaks provide direct experimental signatures of previously unseen compounds produced from the reaction of $\alpha$-pinene with O$_3$. With the aid of quantum chemical calculations, plausible mechanisms for the formation of these new compounds are proposed. These findings provide crucial information on fundamental understanding of the initial steps of $\alpha$-pinene oxidation and the subsequent processes of new particle formation.
- Vacuum ultraviolet free-electron laser,
- Photoionization,
- Mass spectrometry,
- Volatile organic compound,
- Ozonolysis

^†Part of Special Issue "In Memory of Prof. Nanquan Lou on the occasion of his 100th anniversary".
^‡These authors contributed equally to this work.

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References(32)

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